104699-52-7Relevant academic research and scientific papers
Palladium-catalyzed cross-coupling reaction of allyl acetates with pinacol aryl- and vinylboronates
Ortar, Giorgio
, p. 4311 - 4314 (2003)
Pinacol boronates 2 couple efficiently with allyl acetates 1 in the presence of a palladium catalyst prepared in situ from PdCl2 and TFP to give the coupled products 3 in moderate to good yields under mild conditions.
Nickel-catalyzed reductive allylation of aryl bromides with allylic acetates
Cui, Xiaozhan,Wang, Shulin,Zhang, Yuwei,Deng, Wei,Qian, Qun,Gong, Hegui
supporting information, p. 3094 - 3097 (2013/05/23)
This paper highlights Ni-catalyzed allylation of electron-rich aryl bromides with a variety of substituted allylic carbonates using zinc as the terminal reductant, affording E-alkenes regioselectively in good to excellent yields by the addition of aryl to the less hindered allylic carbon. The electron-deficient aryl bromides and chlorides are also highly efficient coupling partners. The Royal Society of Chemistry 2013.
PALLADIUM-CATALYZED CROSS-COUPLING REACTION: DIRECT ALLYLATION OF ARYL BROMIDES WITH ALLYL ACETATE
Yokoyama, Yuusaku,Ito, Sadao,Takahashi, Yumi,Murakami, Yasuoki
, p. 6457 - 6460 (2007/10/02)
Various aryl bromides underwent a palladium-catalyzed cross-coupling reaction with allyl acetate in the presence of hexa-n-butylditin to give the allylated products in very high yields.
