104762-30-3

Basic information

• Product Name: methyl (1R)-4-methyl-1-[(1S)-1-methyl-2-methylidenecyclopentyl]cyclohex-3-ene-1-carboxylate
• CAS NO: 104762-30-3
• Molecular Formula: C₁₆H₂₄O₂
• Molecular Weight: 248.3606
• Mol File: 104762-30-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 306.9°C at 760 mmHg
• Flash Point: 132.1°C
• Density: 1g/cm³
• Vapor Pressure: 0.000748mmHg at 25°C
• Refractive Index: 1.503
• CAS DataBase Reference: methyl (1R)-4-methyl-1-[(1S)-1-methyl-2-methylidenecyclopentyl]cyclohex-3-ene-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (1R)-4-methyl-1-[(1S)-1-methyl-2-methylidenecyclopentyl]cyclohex-3-ene-1-carboxylate(104762-30-3)
• EPA Substance Registry System: methyl (1R)-4-methyl-1-[(1S)-1-methyl-2-methylidenecyclopentyl]cyclohex-3-ene-1-carboxylate(104762-30-3)

Safety Data

• Hazardous Substances Data: 104762-30-3(Hazardous Substances Data)

Upstream product

• 81328-62-3 (2-methylcyclopent-1-enyl)methanol 
• 67209-77-2 2-methyl-cyclopent-1-enecarboxylic acid 
• 4342-60-3 4-methylcyclohex-3-enecarboxylic acid 
• 78-79-5 isoprene 
• 16695-95-7 (4'-methylcyclohex-3'-ene-1-'-yl)carbonyl chloride 
• 104762-26-7 (2-methyl-1-cyclopentenyl)methyl 4-methyl-3-cyclohexene-1-carboxylate 
• 186581-53-3 diazomethane 
• 105164-35-0 4-Methyl-1-(1-methyl-2-methylene-cyclopentyl)-cyclohex-3-enecarboxylic acid 
• 105164-36-1 tert-butyldimethylsilyl 4-methyl-1-(1-methyl-2-methylenecyclopentyl)-3-cyclohexene-1-carboxylate 
• 124787-29-7 (S)-4-Methyl-1-((S)-1-methyl-2-methylene-cyclopentyl)-2-oxo-cyclohexanecarboxylic acid methyl ester 
• 124787-30-0 (S)-4-Methyl-1-((S)-1-methyl-2-methylene-cyclopentyl)-2-oxo-cyclohex-3-enecarboxylic acid methyl ester 

Downstream Products

• 61505-17-7 (+/-)-trichodiene 
• 24493-43-4 (+/-)-bazzanene 
• 82096-03-5 trichodienal 
• 104762-31-4 1-(hydroxymethyl)-4-methyl-1-(1-methyl-2-methylenecyclopentyl)-3-cyclohexene 
• 104762-32-5 1-(hydroxymethyl)-4-methyl-1-(1-methyl-2-methylenecyclopentyl)-3-cyclohexene 

Relevant articles and documents

A Diastereoselective Synthesis of (+/-) Trichodiene

A route to the total synthesis of the title compound is described.The key step involves the sigmatropic of the silyl keteneacetal derived from an allylic β-ketoester.The potential application of this protocol to the construction of the higher tricho

Creation of contiguous quaternary centers by way of [3,3] sigmatropic rearrangements: Synthesis of trichodiene and bazzanene

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