104845-98-9Relevant academic research and scientific papers
Building Units of Oligosaccharides, LXXIX. - Synthesis of the Sequence α-KDO-(2-->4)-α-KDO-(2-->6)-D-GlcN of the "Inner Core" Structure of Lipopolysaccharides
Paulsen, Hans,Stiem, Michael,Unger, Frank M.
, p. 273 - 281 (2007/10/02)
The glycosyl halide of 3-deoxy-D-manno-2-octulosonic acid (KDO) (5) reacts with the D-glucosamine derivative 4 to give the α-(2-->6) glycosidically linked disaccharide 6.After deacetylation from 6 to 7 and conversion into the isopropylidene sugar 16, the
SYNTHESE EINES 3-DESOXY-D-MANNO-2-OCTULOSONSAEURE(KDO)-HALTIGEN TETRASACCHARIDES UND DESSEN STRUKTURVERGLEICH MIT EINEM ABBAU-PRODUKT AUS BAKTERIEN-LIPOPOLYSACCHARIDEN
Paulsen, Hans,Stiem, Michael,Unger, Frank M.
, p. 1135 - 1138 (2007/10/02)
The tetrasaccharide α-KDO-(2-4)-α-KDO-(2-6)-β-D-GlcN(1-6)-D-GlcN 18 has been synthesized in a sequencial oligosaccharide synthesis.This compound is identical with the degradation product which has been isolated from a R-mutant of Salmonella minnesota.Thus
