104858-57-3

Basic information

• Product Name: (Z)-3-Oxo-5-phenyl-pent-4-enoic acid ethyl ester
• CAS NO: 104858-57-3
• Molecular Weight: 218.252
• Mol File: 104858-57-3.mol

Chemical Properties

• CAS DataBase Reference: (Z)-3-Oxo-5-phenyl-pent-4-enoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3-Oxo-5-phenyl-pent-4-enoic acid ethyl ester(104858-57-3)
• EPA Substance Registry System: (Z)-3-Oxo-5-phenyl-pent-4-enoic acid ethyl ester(104858-57-3)

Safety Data

• Hazardous Substances Data: 104858-57-3(Hazardous Substances Data)

Upstream product

• 13148-05-5 ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate 
• 100-52-7 benzaldehyde 

Relevant articles and documents

ANIONIC ACTIVATION OF STABILIZED YLIDES. A HIGHLY Z-STEREOSELECTIVE WITTIG REACTION OF (3-ETHOXYCARBONYL-2-OXOPROPYLIDENE)TRIPHENYLPHOSPHORANE WITH ALIPHATIC ALDEHYDES

Reaction of stabilized ylide 1 with carbonyl partners can be promoted via anionic activation of the ylide; the presence of charge is responsible for the high Z-selectivity in the direct formation of conjugated enones.