1048672-00-9Relevant academic research and scientific papers
Hydroxyl group orientation affects hydrolysis rates of methyl α-septanosides
Markad, Shankar D.,Miller, Shawn M.,Morton, Martha,Peczuh, Mark W.
scheme or table, p. 1209 - 1212 (2010/04/05)
Hydrolysis rates for three related methyl α-septanosides were obtained. The septanosides were synthesized via mCPBA epoxidation and methanolysis of d-mannose, d-galactose, and d-glucose-based oxepines. The rate of hydrolysis correlates with the orientation of hydroxyl groups on the septanose ring in a manner analogous to pyranosides.
Septanose carbohydrates: Synthesis and conformational studies of methyl α-D-glycero-D-idoseptanoside and methyl β-D-glycero-D-guloseptanoside
DeMatteo, Matthew P.,Snyder, Nicole L.,Morton, Martha,Baldisseri, Donna M.,Hadad, Christopher M.,Peczuh, Mark W.
, p. 24 - 38 (2007/10/03)
(Chemical Equation Presented). We report the synthesis of methyl α-D-glycero-D-idoseptanoside (1) and methyl β-D-glycero-D- guloseptanoside (2) and the characterization of their preferred solution conformations by computational chemistry and 1H
