10488-97-8Relevant academic research and scientific papers
Transition-Metal-Free β-C-H Bond Carbonylation of Enamides or Amides with a Trifluoromethyl Group as CO Surrogate for the Synthesis of 1,3-Oxazin-6-ones
Song, Ping,Yu, Peng,Lin, Jin-Shun,Li, Yiqun,Yang, Ning-Yuan,Liu, Xin-Yuan
, p. 1330 - 1333 (2017)
A cascade β-C-H bond trifluoromethylation/C(sp3)-F bond activation/hydrolysis reaction of enamides with Togni's reagent has been disclosed. This formal C-H bond carbonylation reaction utilizes the CF3 group as a CO surrogate to provi
1,3-Oxazin-6-ones from 5(2H)-Isoxazolones
Beccalli, Egle M.,Benincori, Tiziana,Marchesini, Alessandro
, p. 630 - 631 (2007/10/02)
The reaction of 5(2H)-isoxazolones 1 with 1,1-dihalocompounds, in the presence of a base, affords 1,3-oxazin-6-ones 3.
