119873-73-3Relevant academic research and scientific papers
Stereoselective synthesis of disubstituted butadienes via copper-mediated coupling of alkenyl silanes
Blackwell, David T.,Galloway, Warren R. J. D.,Spring, David R.
supporting information; experimental part, p. 2140 - 2144 (2011/11/06)
A strategy is described for the stereoselective synthesis of substituted (E)-, (Z)-, and -disubstituted butadienes from terminal alkynes by the copper-mediated coupling of geometrically-defined alkenyl silanes. Proof-of-concept results that demonstrate the feasibility of this approach are presented. Georg Thieme Verlag Stuttgart · New York.
Enantioselective synthesis of epoxides via Sharpless epoxidation of alkenylsilanols
Chan, T. H.,Chen, L. M.,Wang, D.,Li, L. H.
, p. 60 - 67 (2007/10/02)
Enantioselective synthesis of simple epoxides can be achieved by Sharpless epoxidation of alkenylsilanols followed by protodesilylation of the chiral epoxysilanols.The approach has been applied to the synthesis of frontalin.
Enantioselective Synthesis of Epoxides: Sharpless Epoxidation of Alkenysilanols
Chan, T. H.,Chen, L. M.,Wang, D.
, p. 1280 - 1281 (2007/10/02)
Sharpless epoxidation of the alkenylsilanol (6) followed by protodesilylation gave styrene oxide with high enentiomeric excess.
