104937-84-0Relevant articles and documents
Synthesis of 2-Alkenyl-Tethered Anilines
Denmark, Scott E.,Chi, Hyung Min
, p. 2873 - 2888 (2017/06/27)
Three general routes for the synthesis of (E)-2-alkenyl-tethered anilines have been developed. The first route involves a 3-aza-Cope rearrangement of N -allylic anilines in the presence of a Lewis acid. The requisite N -allylic anilines were prepared by t
Aldehyde selective Wacker oxidations of phthalimide protected allylic amines: A new catalytic route to β3-amino acids
Weiner, Barbara,Baeza, Alejandro,Jerphagnon, Thomas,Feringa, Ben L.
supporting information; experimental part, p. 9473 - 9474 (2009/12/06)
(Chemical Equation Presented) A new method for the synthesis of β3-amino acids is presented. Phthalimide protected allylic amines are oxidized under Wacker conditions selectively to aldehydes using PdCl2 and CuCl or Pd(MeCN)2/s
Enantioselective addition of organolithium reagents to imines mediated by c2-symmetric bis(aziridine) ligands
Andersson, Pher G.,Johansson, Fredrik,Tanner, David
, p. 11549 - 11566 (2007/10/03)
The C2-symmetric bis(aziridine) ligands 1-5 have been screened in the enantioselective addition of organolithium reagents to imines. Ligand 1 (used in stoichiometric amounts) was found to be superior in terms of chemical yield and enantioselect