105017-75-2

Upstream product

• 108-24-7 acetic anhydride 
• 104976-40-1 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol 
• 104976-75-2 2D-(2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-2,3,4-trihydroxy-5-cyclohexen-1-on 
• 104976-74-1 [(3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-2,6-dihydroxy-heptyl]-phosphonic acid dimethyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 105017-77-4 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol 
• 105017-78-5 1D-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-5-C-(hydroxymethyl)-1,2,3,4-cyclohexantetrol 
• 105017-79-6 1D-(1,2,4,5/3)-2,3,4-Tri-O-benzyl-5-C-hydroxymethyl-1,2,3,4-cyclohexantetrol 
• 105017-76-3 1D-(1,2,4/3)-1-O-Acetyl-2,3,4-tri-O-benzyl-5-C-hydroxymethyl-5-cyclohexen-1,2,3,4-tetrol 

Relevant academic research and scientific papers

Cyclitol Reactions, XIII.- Synthesis of Pseudosugars from D-Glucose by Intramolecular Horner-Emmons Olefination

The reaction of the aldehyde 3, prepared from D-glucose diethyl dithioacetal via 1 and 2, with lithium dimethyl methylphosphonat yields the adduct 4.Conversion of 4 into 9 followed by Swern oxidation results in the enone 6.Hydrogenation of 6 leads to pseu