105017-79-6

Upstream product

• 104976-40-1 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol 
• 105017-76-3 1D-(1,2,4/3)-1-O-Acetyl-2,3,4-tri-O-benzyl-5-C-hydroxymethyl-5-cyclohexen-1,2,3,4-tetrol 
• 105017-75-2 1D-(1,2,4/3)-1-O-Acetyl-2,3,4-tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol 
• 104976-75-2 2D-(2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-2,3,4-trihydroxy-5-cyclohexen-1-on 
• 105017-77-4 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol 
• 120090-15-5 (1S,2S,3S,4R)-2,3,4-Tris-benzyloxy-5-[1-methoxy-meth-(E)-ylidene]-cyclohexanol 

Downstream Products

• 105017-80-9 Pseudo-β-L-idopyranose-pentaacetat 

Relevant academic research and scientific papers

Synthetic Methods for the Preparation of D- and L-Pseudo-Sugars from D-Glucose

Starting from D-glucose and using Ferrier rearrangement to obtain the cyclohexanone (1), a convenient synthesis of crystalline pseudo-α-D-glucopyranose (15), its congeners (16) and (17), as well as their partially protected derivatives has been carried out.

Cyclitol Reactions, XIII.- Synthesis of Pseudosugars from D-Glucose by Intramolecular Horner-Emmons Olefination

The reaction of the aldehyde 3, prepared from D-glucose diethyl dithioacetal via 1 and 2, with lithium dimethyl methylphosphonat yields the adduct 4.Conversion of 4 into 9 followed by Swern oxidation results in the enone 6.Hydrogenation of 6 leads to pseu