105017-77-4

Upstream product

• 230636-19-8 (3S,4S,5R)-1,3,4,5-tetrakis(benzyloxy)-6,6-bis(ethylthio)hexan-2-one 
• 213400-35-2 (1S,2S,3S,4R)-2,3,4-tri-O-benzyl-5-(benzyloxymethyl)-cyclohex-5-ene-1,2,3,4-tetrol 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 851542-23-9 C₃₉H₄₆O₄S₂ 
• 851542-24-0 (2R,3S,4R)-2,3,4-tris(benzyloxy)-5-(benzyloxymethyl)hex-5-enal 
• 107960-18-9 (2S,3R,4S,5S)-2,3,4-Tris-benzyloxy-5-ethylsulfanyl-5-hydroxymethyl-cyclohexanol 
• 104976-40-1 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol 
• 105017-75-2 1D-(1,2,4/3)-1-O-Acetyl-2,3,4-tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-5-cyclohexen-1,2,3,4-tetrol 
• 104976-75-2 2D-(2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-2,3,4-trihydroxy-5-cyclohexen-1-on 
• 85716-47-8 (1R,2R,3S,4R)-1,2,3-tri-O-benzyl-6-bromo-4-(bromomethyl)-4-cyclohexene-1,2,3-triol 
• 109923-15-1 (1S,2S,3S,4R)-1-O-benzoyl-5-(benzoyloxymethyl)-2,3,4-tri-O-benzyl-5-cyclohexene-1,2,3,4-tetrol 
• 110372-63-9 1D-(1,2,4,5S/3,5C)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldimethylsiloxy)methyl>-5-C-(ethylthio)-1,2,3,4-cyclohexantetrol 

Downstream Products

• 105017-79-6 1D-(1,2,4,5/3)-2,3,4-Tri-O-benzyl-5-C-hydroxymethyl-1,2,3,4-cyclohexantetrol 
• 105017-78-5 1D-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-5-C-(hydroxymethyl)-1,2,3,4-cyclohexantetrol 
• 1264709-49-0 dibenzyl (1S,4R,5S,6R)-4,5,6-tris(benzyloxy)-3-(([bis(benzoxy)phosphoryl]oxy)methyl)cyclohex-2-en-1-yl phosphate 
• 1264709-40-1 valienol 1,7-diphosphate 
• 109959-12-8 (1R,2S,3S,4R)-2,3,4-tri-O-benzyl-5-(trityloxymethyl)-5-cyclohexene-1,2,3,4-tetrol 
• 109959-16-2 (1R,2S,3S,4R)-1-phthalimido-2,3,4-tri-O-benzyl-5-(hydroxymethyl)-5-cyclohexene-2,3,4-triol 
• 109923-20-8 (1S,2S,3S,4R)-1-phthalimido-2,3,4-tri-O-benzyl-5-(hydroxymethyl)-5-cyclohexene-2,3,4-triol 
• 109923-25-3 (1R,2S,3S,4R)-2,3,4-tri-O-benzyl-1-O-(1-oxo-1H-2,3-benzoxazin-4-yl)-5-(trityloxymethyl)-5-cyclohexene-1,2,3,4-tetrol 
• 109959-17-3 4-((1S,4R,5S,6S)-4,5,6-Tris-benzyloxy-3-trityloxymethyl-cyclohex-2-enyloxy)-benzo[d][1,2]oxazin-1-one 
• 109959-15-1 (1R,2S,3S,4R)-1-phthalimido-2,3,4-tri-O-benzyl-5-(trityloxymethyl)-5-cyclohexene-2,3,4-triol 
• 109923-19-5 (1S,2S,3S,4R)-1-phthalimido-2,3,4-tri-O-benzyl-5-(trityloxymethyl)-5-cyclohexene-2,3,4-triol 
• 109923-17-3 (1R,2S,3S,4R)-1-O-benzoyl-2,3,4-tri-O-benzyl-5-(trityloxymethyl)-5-cyclohexene-1,2,3,4-tetrol 
• 109923-24-2 (1R,2S,3S,4R)-2,3,4-tri-O-benzyl-1-(1,4-dioxo-3,4-dihydro-1H-2,3-benzoxazin-3-yl)-5-(trityloxymethyl)-5-cyclohexene-2,3,4-triol 
• 109923-16-2 (1S,2S,3S,4R)-2,3,4-tri-O-benzyl-5-(trityloxymethyl)-5-cyclohexene-1,2,3,4-tetrol 

Relevant academic research and scientific papers

Nucleotidylation of unsaturated carbasugar in validamycin biosynthesis

Validamycin A is a member of microbial-derived C7N-aminocyclitol family of natural products that is widely used as crop protectant and the precursor of the antidiabetic drug voglibose. Its biosynthetic gene clusters have been identified in seve

α-Glucosidase Inhibitors, 5.- Investigations towards a Synthesis of C1-Branched Cyclitols from D-Glucose

The glucose derivatives 1 and 2 were transformed by Ferrier rearrangement as one of the reaction steps into the cyclitol derivatives 3a,b and 4a,b, respectively.The attachment of a functional C1-side chain at the carbonyl group was tested with

Cyclitol Reactions, XIII.- Synthesis of Pseudosugars from D-Glucose by Intramolecular Horner-Emmons Olefination

The reaction of the aldehyde 3, prepared from D-glucose diethyl dithioacetal via 1 and 2, with lithium dimethyl methylphosphonat yields the adduct 4.Conversion of 4 into 9 followed by Swern oxidation results in the enone 6.Hydrogenation of 6 leads to pseu

DISPLACEMENT OF "PSEUDOANOMERIC" HYDROXYL GROUPS BY USING THE DIETHYL AZODICARBOXYLATE-TRIPHENYLPHOSPHINE SYSTEM

1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-(trityloxymethyl)-5-cyclohexene-1,2,3,4-tetrol (5a) and its 1L-(1,3/2,4) isomer (5b) were prepared from D-glucose, and they underwent ready mutual interconversion through an SN2 procedure employing a benzoic ac