105114-53-2

Basic information

• Product Name: 1,3-Dioxane, 2-(4-bromophenyl)-5,5-dimethyl-
• CAS NO: 105114-53-2
• Molecular Formula: C12H15BrO2
• Molecular Weight: 271.154
• Mol File: 105114-53-2.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxane, 2-(4-bromophenyl)-5,5-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxane, 2-(4-bromophenyl)-5,5-dimethyl-(105114-53-2)
• EPA Substance Registry System: 1,3-Dioxane, 2-(4-bromophenyl)-5,5-dimethyl-(105114-53-2)

Safety Data

• Hazardous Substances Data: 105114-53-2(Hazardous Substances Data)

Usage

Physical state

Colorless liquid

Molecular weight

249.14 g/mol

Uses

a. Solvent
b. Intermediate in the synthesis of pharmaceuticals and agrochemicals
c. Production of perfumes, dyes, and specialty chemicals

Hazard classification

Classified as a hazardous substance due to potential toxicity and carcinogenicity

Handling and disposal

Should be handled and disposed of with care to minimize impact on human health and the environment

Upstream product

• 1122-91-4 4-bromo-benzaldehyde 
• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 62-53-3 aniline 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 146308-15-8 4'-(5,5-dimethyl-1,3-dioxan-2-yl)-3,4,5-trimethoxy-N-toluene-p-sulfonyldiphenylamine 
• 107816-45-5 N-(4-methoxyphenyl)-4-<2-(5,5-dimethyl-1,3-dioxanyl)>acetanilide 
• 106456-88-6 4-(5,5-dimethyl-1,3-dioxan-2-yl)benzaldehyde 
• 321733-38-4 1-[4-(5,5-dimethyl-1,3-dioxan-2-yl)phenyl]piperidine 
• 307537-99-1 2-(4-allylphenyl)-5,5-dimethyl-1,3-dioxane 
• 305344-39-2 2-(4-(5,5-dimethyl-1,3-dioxan-2-yl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 777064-01-4 4-(5,5-dimethyl-1,3-dioxan-2-yl)dithiobenzoic acid 
• 71141-58-7 4-formyldithiobenzoic acid 
• 120085-99-6 2,9‐bis(4-formylphenyl)‐1,10‐phenanthroline 
• 223449-11-4 C₅₂H₅₀N₄O₄ 
• 105114-54-3 3,3-(2,2-dimethyl-trimethylenedioxy)-11β-[4-(5,5-dimethyl-1,3-dioxan-2-yl)-phenyl]-9-estrene-5α,17β-diol 
• 1260425-55-5 (bis(4?(bis(4?methoxyphenyl)amino)phenyl)amino)benzaldehyde 
• 949161-93-7 2-(4-iodo-phenyl)-5,5-dimethyl-[1,3]dioxane 
• 106456-80-8 meso-tetrakis<4-(1,3-dioxa-5,5-dimethylcyclohex-2-yl)phenyl>porphyrin 

Relevant articles and documents

Grafting of oligoaniline on CdSe nanocrystals: Spectroscopic, electrochemical and spectroelectrochemical properties of the resulting organic/inorganic hybrid

We have synthesised a new organic/inorganic hybrid, in which electroactive aniline tetramer is grafted on the surface of quasi-monodispersed CdSe nanocrystals. The grafting reaction consists of two steps. First initial nanocrystal surface ligands (TOPO) a

Visible-light-induced acetalization of aldehydes with alcohols

In this work, we have achieved a simple and general method for acetalization of aldehydes by means of a photochemical reaction under low-energy visible light irradiation. A broad range of aromatic, heteroaromatic, and aliphatic aldehydes have been protected under neutral conditions in good to excellent yields using a catalytic amount of Eosin Y as the photocatalyst. Our visible light mediated acetalization strategies are successful for more challenging acid-sensitive aldehydes and sterically hindered aldehydes. Notably, this protocol is chemoselective to aldehydes, while ketones remain intact.

Synthesis of 1,5-substituted anthracenes by means of Kumada coupling and their derivatization

Herein, we present a method to access a series of 1,5-functionalized anthracenes through Kumada coupling. All syntheses start from readily available 1,5-dichloroanthracene. The so-formed anthracenes are further derivatized to enable, for example, attachme