10519-73-0Relevant articles and documents
Deprotonation of Methylarene Cation Radicals in Acetonitrile. An Unexpected Second-Order Mechanism
Parker, Vernon D.,Tilset, Mats
, p. 6371 - 6377 (1986)
The kinetics of the deprotonation reactions of the cation radicals of several methylarenes were studied by derivative cyclic voltammetry (DCV) and derivative linear-sweep voltammetry (DLSV) in acetonitrile.The kinetic data indicate rate law and suggest a
Remarkable effect of water on functionalization of the phenyl ring in methyl-substituted benzene derivatives with F-TEDA-BF4
Kralj, Petra,Zupan, Marko,Stavber, Stojan
, p. 3880 - 3888 (2007/10/03)
Various N-F reagents reacted with hexamethylbenzene (1) forming side chain substituted alkoxides or esters in protic solvents, Ritter type side chain functionalization was observed in acetonitrile in the presence of trifluoroacetic acid, while in aqueous