105198-75-2

Basic information

• Product Name: Propanoyl chloride, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-
• CAS NO: 105198-75-2
• Molecular Formula: C19H23ClO2Si
• Molecular Weight: 346.929
• Mol File: 105198-75-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Propanoyl chloride, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanoyl chloride, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-(105198-75-2)
• EPA Substance Registry System: Propanoyl chloride, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-(105198-75-2)

Safety Data

• Hazardous Substances Data: 105198-75-2(Hazardous Substances Data)

Upstream product

• 166194-08-7 methyl 3-<(tert-butyldiphenylsilyl)oxy>propionate 
• 127047-71-6 3-(tert-butyldiphenylsilyloxy)propan-1-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 310409-17-7 methyl 3-(tert-butyldiphenylsilyloxy)propanoic acid 

Downstream Products

• 145237-18-9 5-(tert-Butyl-diphenyl-silanyloxy)-3-oxo-2-(triphenyl-λ⁵-phosphanylidene)-pentanoic acid tert-butyl ester 
• 105198-76-3 5-(tert-Butyl-diphenyl-silanyloxy)-1-trimethylsilanyl-pent-1-yn-3-one 
• 916836-52-7 N-norarachidonyl-3-(t-butyl-diphenylsilyloxy)propionamide 
• 225114-87-4 (S)-5-((tert-butyldiphenylsilyl)oxy)-1-(trimethylsilyl)pent-1-yn-3-ol 
• 105198-78-5 tert-Butyl-diphenyl-[(S)-3-(tetrahydro-pyran-2-yloxy)-pent-4-ynyloxy]-silane 
• 105198-77-4 2-{(S)-1-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-3-trimethylsilanyl-prop-2-ynyloxy}-tetrahydro-pyran 
• 918828-70-3 C₃₅H₃₇FN₂O₇SSi 
• 918828-71-4 benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate 
• 918667-14-8 ethyl (Z)-5-([tert-butyl(diphenyl)silyl]oxy)-2-fluoro-2-pentenoate 
• 918828-69-0 (Z)-5-([tert-butyl(diphenyl)silyl]oxy)-2-fluoro-2-penten-1-ol 

Relevant articles and documents

Tandem reduction-olefination of triethyl 2-acyl-2-fluoro-2-phosphonoacetates and a synthetic approach to Cbz-Gly-Ψ[(Z)-CF{double bond, long}C]-Gly dipeptide isostere

(Z)-α-Fluoro-α,β-unsaturated esters (Z)-7a-f were stereoselectively prepared by a tandem reduction-olefination of triethyl 2-acyl-2-fluoro-2-phosphonoacetates 6a-f with NaBH4 in EtOH. A concise synthesis of Cbz-Gly-Ψ[(Z)-CF{double bond, long}C]-Gly (26) as a dipeptide isostere was achieved via the tandem reduction-olefination of the corresponding 2-acyl-2-fluoro-2-phosphonoacetate 20.

Bruchins - Mitogenic 3-(hydroxypropanoyl) esters of long chain diols from weevils of the bruchidae

Mono- and bis 3-(hydroxypropanoyl) esters of long chain, unsaturated diols have been isolated and identified from two genera of the family Bruchidae, and have been shown to be responsible for the mitogenic activity observed on pea pods resulting from oviposition by the pea weevil, Bruchus pisorum. The mitogenic compounds have been characterized and synthesized.