105279-34-3Relevant academic research and scientific papers
Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
Yerien,Barata-Vallejo,Camps,Cristófalo,Cano,Uhrig,Postigo
, p. 2274 - 2282 (2017)
Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily available RFI.
Nucleophilic perfluoroalkylation of aldehydes, ketones, imines, disulfides, and diselenides
Pooput, Chaya,Dolbier Jr., William R.,Medebielle, Maurice
, p. 3564 - 3568 (2007/10/03)
Using a procedure analogous to that developed for nucleophilic trifluoromethylation, the perfluoroalkyl anion reagents created by mixing C 2F5I and n-C4F9I with tetrakis(dimethylamino)ethylene (TDAE) were effective in their nucleophilic reactions with aldehydes, ketones, imines, disulfides, and diselenides. Irradiation proved beneficial in the aldehyde and ketone reactions.
Synthesis of (perfluoroalkylsulfonyl)benzenes
Joglekar, Bharati,Miyake, Tomoko,Kawase, Ritsu,Shibata, Katsuyoshi,Muramatsu, Hiroshige,Matsui, Masaki
, p. 123 - 126 (2007/10/03)
4-Substituted (perfluoroalkylsulfonyl)benzenes have been synthesized by the oxidation of 4-substituted (perfluoroalkylthio)benzenes with hydrogen peroxide, anhydrous chromic oxide and potassium permanganate in good yields. 4-(Perfluoroalkylsulfonyl)anilines have been also prepared by the reduction of the corresponding nitrobenzenes. - Keywords: Synthesis; (Perfluoroalkylsulfonyl)benzenes; NMR spectroscopy; Mass spectrometry
Perfluoroalkyl-Chalcogenation of Alkynes
Ueda, Yasufumi,Kanai, Masatomi,Uneyama, Kenji
, p. 2273 - 2277 (2007/10/02)
Perfluoroalkyl-telluration of alkynes has been performed by a (PhTe)2-NaBH4-RfX system at a low temperature (-40, -80, or -100 deg C) to give 2-(perfluoroalkyl)vinyl tellurides.Meanwhile, perfluoroalkyl-sulfenylation and perfluoroalkyl-selenation were les
