105363-56-2Relevant academic research and scientific papers
Haloisoquinoline carboxamide
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, (2008/06/13)
Compounds of the invention have the general structure STR1 X, Y or Z are, respectively independently, H, F or an isotope thereof, Br or an isotope thereof, I or an isotope thereof, At or an isotope thereof, (R 1)W or (R 2)V and R is --(R 1)W, when W is H
"Syn-Effect" in the Conversion of (E)-Vinylic Sulfones to the Corresponding Allylic Sulfones
Hirata, Takaki,Sasada, Yoshihiro,Ohtani, Takashi,Asada, Takahiro,Kinoshita, Hideki,et al.
, p. 75 - 96 (2007/10/02)
It was found that (E)-vinylic sulfones preferentially afford (Z)-allylic sulfones as kinetically-controlled products by treatment with a base under mild conditions, while (Z)-vinylic sulfones give (E)-allylic sulfones.Such stereochemical relationship was
Remote Participation during Photooxidation at Sulfur. Eidence for Sulfurane Intermediates
Clennan, E. L.,Yang, Kang
, p. 4477 - 4487 (2007/10/02)
The photooxidations of geminally substituted γ-hydroxy sulfides results in formation of unusual oxidative elimination products.Detailed spectral data and the independent synthesis of a close analogue provide compelling evidence for the structures of these
EPOXIDE RING OPENING BY α-SULFONYL CARBANIONS. SYNTHESIS OF γ-HYDROXY SULFONES AND TRIFLONES
Nwaukwa, Stephen O.,Lee, Susanna,Keehn, Philip M.
, p. 309 - 330 (2007/10/02)
γ-Hydroxy sulfones and triflones are obtained in moderate to excellent yields when n-butyl lithium is added to a mixture of sulfone and epoxide in toluene at 65 deg C followed by heating from four to twenty hours at 110 deg C.
