105374-37-6

Basic information

• Product Name: tricarbonyl(1-4-η-2-((E)-isobutylidene)-3-phenyl-1,3-propanediyl)iron
• CAS NO: 105374-37-6
• Molecular Weight: 312.148
• Mol File: 105374-37-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tricarbonyl(1-4-η-2-((E)-isobutylidene)-3-phenyl-1,3-propanediyl)iron(CAS DataBase Reference)
• NIST Chemistry Reference: tricarbonyl(1-4-η-2-((E)-isobutylidene)-3-phenyl-1,3-propanediyl)iron(105374-37-6)
• EPA Substance Registry System: tricarbonyl(1-4-η-2-((E)-isobutylidene)-3-phenyl-1,3-propanediyl)iron(105374-37-6)

Safety Data

• Hazardous Substances Data: 105374-37-6(Hazardous Substances Data)

Upstream product

• 13463-40-6 iron pentacarbonyl 
• 13643-05-5 4-methyl-1,2-pentadiene 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Organic Syntheses via Transition Metal Complexes, 18. - A Novel Type of Carbonyl Olefination by Means of Allenes via a Template-Induced Formation of (Trimethylenemethane)tricarbonyliron Complexes

On photolysis in the presence of Fe(Co)5 allenes and aldehydes give (trimethylenemethane)tricarbonyliron complexes 5 and 5'.The reaction is highly stereospecific and involves the intermediate formation of ?-allyl-?-complexes, which spontaneously eliminate CO2 to give 5 and 5'.To our knowledge, this is the first example of a carbonyl olefination by means of a quarternary carbon of a cumulene.The trimethylenemethane ligand of 5 may be isomerised at 180 deg C without decomposition via rotation of substituents around the C=C bonds.