105467-74-1

Basic information

• Product Name: dibenzo[a,j]acridin-14(7H)-one
• CAS NO: 105467-74-1
• Molecular Formula: C₂₁H₁₃NO
• Molecular Weight: 295.334
• Mol File: 105467-74-1.mol

Chemical Properties

• Boiling Point: 539.7°C at 760 mmHg
• Flash Point: 208.7°C
• Density: 1.301g/cm³
• Vapor Pressure: 1.03E-11mmHg at 25°C
• Refractive Index: 1.755
• CAS DataBase Reference: dibenzo[a,j]acridin-14(7H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: dibenzo[a,j]acridin-14(7H)-one(105467-74-1)
• EPA Substance Registry System: dibenzo[a,j]acridin-14(7H)-one(105467-74-1)

Safety Data

• Hazardous Substances Data: 105467-74-1(Hazardous Substances Data)

Upstream product

• 121677-96-1 2-(N-[2]naphthyl-benzimidoyloxy)-[1]naphthoic acid methyl ester 
• 1163-05-9 dibenzacridine N-oxide 
• 1210-03-3 3-hydroxy-1-methylbenzoquinoline 
• 5419-02-3 1-dimethylaminomethyl-naphthalen-2-ol 
• 224-42-0 dibenz[a,j]acridine 
• 2217-43-8 6-amino-1,2,3,4-tetrahydronaphthalene 
• 105467-77-4 1,2,3,4-tetrahydrodibenzacridine 
• 105483-69-0 1,4,10,13-tetrahydrodibenzacridine 
• 105467-76-3 1,4,8,9-tetrahydrodibenzacridine 
• 947-65-9 methyl 2-hydroxy-1-naphthoate 
• 201230-82-2 carbon monoxide 
• 532-18-3 2,2'-dinaphthylamine 

Relevant articles and documents

Palladium/copper Co-catalyzed oxidative C-H/C-H carbonylation of diphenylamines: A way to access acridones

An efficient palladium/copper co-catalyzed oxidative double C(sp2)-H functionalization/carbonylation of diphenylamines for synthesis of acridones has been developed. This method utilizes readily available starting materials and mild reaction conditions. The protocol provides a simple, efficient, and atomeconomic way to access acridones. Notably, the present protocol has excellent functional group tolerance and application value.

Method for synthesizing acridone derivatives by means of palladium-copper co-catalysis

The invention discloses a method for synthesizing acridone derivatives by means of palladium-copper co-catalysis. The method comprises the steps that on the condition that palladium chloride, copper pivalate and di-tert-butyl peroxide or oxygen co-exist, diphenylamine compounds including symmetric diphenylamine and asymmetric diphenylamine are dissolved in an anhydrous organic solvent, all the materials are mixed to be uniform, a reaction is conducted for 20 h to 30 h under the condition of 80 DEG C to 120 DEG C in a carbon monoxide atmosphere, separation and purification are conducted, and the acridone derivatives can be obtained. According to the method for synthesizing the acridone derivatives by means of palladium-copper co-catalysis, the preparation method is simple, the diphenylamine compounds which are simple and easy to obtain are used as the raw materials, and the acridone derivatives are directly constructed through C-H/C-H oxidative carbonylation; the preparation condition is mild, and the target product can be obtained in a high-selectivity mode at 80 DEG C to 120 DEG C; the acridone derivatives have good substrate applicability, the range of substrates is greatly expanded, and the acridone derivatives have a great application prospect in biological medicine and materials and the like.

Synthesis of benzoacridines by a photochemical route

A facile synthesis of benzoacridines by photoring-closure of substituted 2-styrylquinolin-4-(1H)ones is described.

Synthesis of Potential Metabolites of Dibenzacridine: Dihydro Diols and Phenols

The potential trans dihydro diol metabolites of the carcinogen dibenzacridine (1) were prepared.The dihydro diols trans-1,2-dihydroxydibenzacridine (12) and trans-3,4-dihydro-3,4-dihydroxydibenzacridine (13) were prepared by Prevost reactio