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10548-46-6

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10548-46-6 Usage

Chemical Properties

Off-White Solid

Uses

1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin , tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.

Check Digit Verification of cas no

The CAS Registry Mumber 10548-46-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,5,4 and 8 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 10548-46:
(7*1)+(6*0)+(5*5)+(4*4)+(3*8)+(2*4)+(1*6)=86
86 % 10 = 6
So 10548-46-6 is a valid CAS Registry Number.
InChI:InChI=1/C27H28O5/c1-4-10-20(11-5-1)16-28-24-23-19-31-27(32-23)26(30-18-22-14-8-3-9-15-22)25(24)29-17-21-12-6-2-7-13-21/h1-15,23-27H,16-19H2/t23-,24-,25+,26-,27-/m1/s1

10548-46-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,6-Anhydro-2,3,4-tri-<i>O</i>-benzyl-β-<small>D</small>-glucopyranose

1.2 Other means of identification

Product number -
Other names (1R,2R,3S,4R,5R)-2,3,4-tris(phenylmethoxy)-6,8-dioxabicyclo[3.2.1]octane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10548-46-6 SDS

10548-46-6Relevant articles and documents

Trimethylsilyl triflate mediated chemoselective condensation of arylsulfenyl glycosides

Sliedregt,Van Der Marel,Van Boom

, p. 4015 - 4018 (1994)

Condensation of a fully benzoylated phenylsulfenyl glycoside with either benzylated or benzoylated phenylthio glycosyl acceptors under the agency of trimethylsilyl triflate proceeds with a good degree of chemoselectivity in the presence of the scavenger t

One-pot, highly stereoselective synthesis of dithioacetal-α,α-diglycosides

Céspedes Dávila, Maria F.,Schneider, Jérémy P.,Godard, Amélie,Hazelard, Damien,Compain, Philippe

supporting information, (2018/04/24)

A one-step access to dithioacetal-α,α-diglycosides is reported. The synthetic strategy is based on the thioacetalization of aldehydes or ketones via highly stereoselective ring-opening of 1,6 anhydrosugars with bis(trimethylsilyl)sulfide.

Total synthesis of herbicidin C and aureonuclemycin: Impasses and new avenues

Hager, Dominik,Paulitz, Christian,Tiebes, Joerg,Mayer, Peter,Trauner, Dirk

, p. 10784 - 10801 (2013/11/19)

The undecose nucleoside antibiotics herbicidin C and aureonuclemycin are biologically highly active and represent challenging targets for total synthesis. Herein, the gradual evolution of our synthetic strategy toward these natural products is described in detail. The initial route encompasses metalate addition chemistry but suffers from poor stereochemical control. In contrast, the ultimately successful strategy benefits from a variety of reagent-controlled stereoselective transformations, including a surprisingly facile and highly diastereoselective N-glycosylation process. The presented work also describes new building blocks that might find further application in carbohydrate chemistry.

Gold-catalyzed glycosidations: Synthesis of 1,6-anhydro saccharides

Thadke, Shivaji A.,Hotha, Srinivas

experimental part, p. 5912 - 5914 (2010/11/18)

Various 1,6-anhydro sugars are synthesized utilizing salient features of gold-catalyzed glycosidations. All the reactions occurred under mild conditions in the presence of 7 mol % of AuBr3 enabling easy synthesis of 1,6-anhydro sugars from corr

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