105488-77-5Relevant academic research and scientific papers
NMR observation of trialkylphosphite-palladium(II) and ruthenium(II) complexes in supercritical carbon dioxide
Kayaki, Yoshihito,Suzuki, Tomoyuki,Noguchi, Yushi,Sakurai, Satoshi,Imanari, Mamoru,Ikariya, Takao
, p. 424 - 425 (2002)
A supercritical fluid nuclear magnetic resonance (scNMR) spectroscopic method has been developed using a commercially available NMR spectrometer equipped with a high-pressure zirconia cell, revealing that trialkylphosphite ligands are highly effective for increasing the solubility of dichloropalladium(II) and dichlororuthenium(II) complexes in supercritical carbon dioxide (scCO2).
A Novel Catalytic Synthesis of Vinyl Carbamates from Carbon Dioxide, Diethylamine, and Alkynes in the Presence of Ru3(CO)12
Sasaki, Yoshiyuki,Dixneuf, Pierre H.
, p. 790 - 791 (1986)
The reaction of carbon dioxide, diethylamine, and hex-1-yne (1a) or phenylacetylene (1b), catalysed by Ru3(CO)12, gave the vinyl carbamates (2a), (3a), and (4a) or (2b) and (3b).
Regioselective Re(I)-catalyzed coupling of terminal alkynes, Et 2NH, and CO2 leading to anti-Markovnikov adducts
Jiang, Jia-Li,Hua, Ruimao
, p. 953 - 955 (2006)
ReBr(CO)5-catalyzed addition of Et2NH and CO 2 to terminal alkynes afforded anti-Markovnikov adducts of alkenyl carbamates in good to excellent yield and high regioselectivity.
Ruthenium catalyzed regioselective coupling of terminal alkynes, amine and carbon dioxide leading to anti-Markovnikov adducts
Watile, Rahul A.,Bhanage, Bhalchandra M.
, p. 23022 - 23026 (2014/06/24)
RuCl2(p-cymene)/DPPE catalyzed addition of secondary amines and CO2 to terminal alkynes affording anti-Markovnikov adducts of vinyl carbamates in good yield with excellent regioselectivity is reported. The catalyst, consisting of lab
Catalytic Synthesis of Vinyl Carbamates from Carbon Dioxide and Alkynes with Ruthenium Complexes
Mahe, Roger,Sasaki, Yoshiyuki,Bruneau, Christian,Dixneuf, Pierre H.
, p. 1518 - 1523 (2007/10/02)
Terminal alkynes react with carbon dioxide and secondary amines in the presence of ruthenium complexes to afford vinyl carbamates in one step.The reaction has been performed with phenylacetylene, hexyne, and acetylene and with dialkylamines, morpholine, p
ONE-STEP SYNTHESIS OF VINYL CARBAMATES CATALYZED BY MONONUCLEAR RUTHENIUM COMPLEXES VIA ADDITION OF CARBON DIOXIDE AND AMINE TO TERMINAL ALKYNES
Mahe, R.,Dixneuf, P. H.,Lecolier, S.
, p. 6333 - 6336 (2007/10/02)
Terminal alkynes with secondary amines (dimethylamine, diethylamine, piperidine, morpholine,) and CO2 in the presence of mononuclear ruthenium catalysts, afford the vinyl carbamates R1CH=CH-O-CONR2.The reaction studies suggest, as th
