10554-29-7Relevant academic research and scientific papers
Total synthesis of saturated and unsaturated di-trans-N-substituted cyclam-based macrocycles through a versatile intermediate
Barros, M. Teresa,Si?eriz, Fernando
, p. 4759 - 4764 (2007/10/03)
A total synthesis of di-trans-N-substituted cyclam-type macrocycles through a versatile intermediate is described for the first time. This synthesis uses readily available low-cost commercial reagents. This synthesis was designed in such a way that the pr
PHOTODECARBOXYLATIVE CHLORINATION OF CARBOXYLIC ACIDS VIA THEIR BENZOPHENONE OXIME ESTERS
Hasebe, Masato,Tsuchiya, Takashi
, p. 6287 - 6290 (2007/10/02)
Decarboxylative chlorination of various aromatic and aliphatic carboxylic acids is performed successfully by the photolysis of their benzophenone oxime esters in carbon tetrachloride and corresponding chloro compounds are prepared in good yields.High selective generation of the certain radical and efficiency of the stable radical precursor, benzophenone oxime ester, afford much advantage for radical chemistry.
