105638-72-0Relevant articles and documents
Preparation and utility of cyclic enol carbonates
Maddess, Matthew L.,Lautens, Mark
, p. 1399 - 1408 (2007/10/03)
Treatment of iodo carbonates with LiHMDS at low temperature readily affords cyclic enol carbonates with either five- or six-membered rings. Reaction with potassium fert-butoxide results in the in situ formation of an enolate which after transmetallation p
Carboxylative Coupling of Propargylic Alcohols with Allyl Chloride
Iritani, Koji,Yanagihara, Naoto,Utimoto, Kiitiro
, p. 5499 - 5501 (2007/10/02)
Palladium-mediated reaction of lithium 2-alkynyl carbonates with allyl chloride affords cyclic carbonates whose alkaline hydrolysis gives keto alcohols in good yields.The combination of the above procedure with the formation of lithium 2-alkynolates from