105643-16-1

Basic information

• Product Name: Benzenemethanol, 4-chloro-a-ethenyl-, acetate
• CAS NO: 105643-16-1
• Molecular Formula: C11H11ClO2
• Molecular Weight: 210.66
• Mol File: 105643-16-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-chloro-a-ethenyl-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-chloro-a-ethenyl-, acetate(105643-16-1)
• EPA Substance Registry System: Benzenemethanol, 4-chloro-a-ethenyl-, acetate(105643-16-1)

Safety Data

• Hazardous Substances Data: 105643-16-1(Hazardous Substances Data)

Upstream product

• 58824-54-7 p-chlorophenylvinylcarbinol 
• 108-24-7 acetic anhydride 
• 104-88-1 4-chlorobenzaldehyde 
• 106-39-8 bromochlorobenzene 
• 75-36-5 acetyl chloride 

Downstream Products

• 170938-14-4 (E)-3-(4-chlorophenyl)allyl acetate 
• 870620-91-0 (E)-1-chloro-4-(3-phenyl-1-propen-1-yl)benzene 
• 1152652-36-2 (E)-1-[3-(4-chlorophenyl)allyl]-4-methylpiperazine 
• 1152652-64-6 (E)-1-[3-(4-chlorophenyl)allyl]-1,2,3,4-tetrahydroquinoline 
• 103979-26-6 3,4-bis-(4-chlorophenyl)hexa-1,5-diene 

Relevant articles and documents

Regiocontrol and Stereoselectivity in Tungsten-Bipyridine Catalysed Allylic Alkylation

Tungsten-bipyridine complexes, generated in situ, catalyse the allylic alkylation of isocinnamyl methyl carbonate by dimethyl sodiomalonate with complete syn-stereoselectivity.When para substituted aryl-allyl methyl carbonates are employed, the regioselectivity correlates with Swain-Lupton parameters.Cross-over experiments demonstrate that the reactions do not proceed via the conventional 0> -> II allyl>+ -> 0 allyl-Nu> catalytic cycle.

A Re2O7catalyzed cycloetherification of monoallylic diols

A Re2O7catalyzed cycloetherification of monoallylic diols is described. The reaction features short reaction time, mild reaction conditions and exclusive E selectivity. A wide range of monoallylic alcohols with alkyl or aryl substituents on olefin smoothly undergo ring closure to deliver corresponding oxa-heterocycles. The reaction is also operationally simple and not sensitive to air and moisture.

Highly efficient kinetic resolution of allylic alcohols with terminal double bond

In this study, the lipase-catalyzed kinetic resolution (Novozyme 435) was employed to prepare chiral allylic alcohols and acetates with terminal double bonds in enantiomeric excesses ranging from 94 to >99 %.