105643-16-1

Upstream product

• 58824-54-7 p-chlorophenylvinylcarbinol 
• 75-36-5 acetyl chloride 
• 106-39-8 bromochlorobenzene 
• 104-88-1 4-chlorobenzaldehyde 
• 108-24-7 acetic anhydride 

Downstream Products

• 164527-44-0 diethyl (E)-3-(4-chlorophenyl)prop-2-enyl phosphate 
• 360065-87-8 benzyl-[3-(4-chlorophenyl)allyl]amine 
• 164527-51-9 (E)-dimethyl 2-(3-(4-chlorophenyl)allyl)malonate 
• 164527-50-8 (+)-2-[1-(4-chloro-phenyl)-allyl]-malonic acid dimethyl ester 
• 870620-91-0 (E)-1-chloro-4-(3-phenyl-1-propen-1-yl)benzene 
• 170938-14-4 (E)-3-(4-chlorophenyl)allyl acetate 
• 103979-26-6 3,4-bis-(4-chlorophenyl)hexa-1,5-diene 

Relevant academic research and scientific papers

Regiocontrol and Stereoselectivity in Tungsten-Bipyridine Catalysed Allylic Alkylation

Tungsten-bipyridine complexes, generated in situ, catalyse the allylic alkylation of isocinnamyl methyl carbonate by dimethyl sodiomalonate with complete syn-stereoselectivity.When para substituted aryl-allyl methyl carbonates are employed, the regioselectivity correlates with Swain-Lupton parameters.Cross-over experiments demonstrate that the reactions do not proceed via the conventional 0> -> II allyl>+ -> 0 allyl-Nu> catalytic cycle.

Size-Exclusion Borane-Catalyzed Domino 1,3-Allylic/Reductive Ireland–Claisen Rearrangements: Impact of the Electronic and Structural Parameters on the 1,3-Allylic Shift Aptitude

The reductive Ireland–Claisen rearrangement through borane-mediated hydrosilylation is reported. The method employs a borane catalyst with a special structural design and affords access to synthetically relevant products with high diastereoselectivity. Depending on electronic and structural parameters, the reaction can be coupled with a 1,3-allylic shift, thus the valence isomer of the Ireland–Claisen product is formed.

A Re2O7catalyzed cycloetherification of monoallylic diols

A Re2O7catalyzed cycloetherification of monoallylic diols is described. The reaction features short reaction time, mild reaction conditions and exclusive E selectivity. A wide range of monoallylic alcohols with alkyl or aryl substituents on olefin smoothly undergo ring closure to deliver corresponding oxa-heterocycles. The reaction is also operationally simple and not sensitive to air and moisture.

Kinetic Resolution of Racemic and Branched Monosubstituted Allylic Acetates by a Ruthenium-Catalyzed Regioselective Allylic Etherification

We demonstrated the kinetic resolution of racemic and branched monosubstituted allylic acetates by a ruthenium-catalyzed regioselective allylic etherification. The reaction was effectively catalyzed by the chiral ruthenium catalyst, which was generated by [RuCl2(p-cymene)]2 and (S,S)-iPr-pybox and a catalytic amount of TFA, and both the allylic etherification product and recovered allylic acetate were obtained as an enantiomerically enriched form with up to a 103 s value.

Highly efficient kinetic resolution of allylic alcohols with terminal double bond

In this study, the lipase-catalyzed kinetic resolution (Novozyme 435) was employed to prepare chiral allylic alcohols and acetates with terminal double bonds in enantiomeric excesses ranging from 94 to >99 %.

Structure-activity relationships of (1'S)-1'-acetoxychavicol acetate, a major constituent of a Southeast Asian condiment plant Languas galanga, on the inhibition of tumor-promoter-induced Epstein-Barr virus activation

The structure-activity relationships of (1'S)-1'-acetoxychavicol acetate (ACA), a cancer chemopreventive agent of food origin, were investigated in an inhibitory test of tumor promoter teleocidin B-4-induced Epstein-Barr virus (EBV) activation in Raji cel

Chirale Phosphanodihydrooxazole in der asymmetrischen Katalyse: Wolfram-katalysierte allylische Substitution

Stichworte: Alkylierungen * Asymmetrische Synthesen * Dihydrooxazole * Katalyse * Wolframverbindungen