58824-54-7

Basic information

• Product Name: Benzenemethanol, 4-chloro-a-ethenyl-
• CAS NO: 58824-54-7
• Molecular Formula: C9H9ClO
• Molecular Weight: 168.623
• Mol File: 58824-54-7.mol
• Article Data: 64

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-chloro-a-ethenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-chloro-a-ethenyl-(58824-54-7)
• EPA Substance Registry System: Benzenemethanol, 4-chloro-a-ethenyl-(58824-54-7)

Safety Data

• Hazardous Substances Data: 58824-54-7(Hazardous Substances Data)

Upstream product

• 7270-47-5 4-chlorophenylmagnesium iodide 
• 107-02-8 acrolein 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 106-39-8 bromochlorobenzene 
• 104-88-1 4-chlorobenzaldehyde 
• 3536-96-7 vinylmagnesium chloride 
• 75-77-4 chloro-trimethyl-silane 
• 593-60-2 Vinyl bromide 
• 1826-67-1 vinyl magnesium bromide 
• 2768-02-7 (vinyl)trimethoxylsilane 
• 103979-29-9 (E)-1-(4-chlorophenyl)-3-chloropropene 
• 7335-27-5 ethyl 4-chlorobenzoate 
• 91254-62-5 2-hydroxy-6-oxo-6-(p-chlorophenyl)hexa-2,4-dienoic acid 
• 3946-29-0 3,4'-Dichloropropiophenone 

Downstream Products

• 105643-15-0 4-chlorocinnamyl acetate 
• 105643-16-1 (1'R,S)-1-(4-chlorophenyl)-2-propene-1-acetate 
• 6285-05-8 4'-chloropropiophenone 
• 496789-08-3 1-(4'-chlorophenyl)-prop-2-enyl methyl carbonate 
• 1240503-34-7 2-[1-(p-chlorophenyl)allyl]-3-hydroxy-5,5-dimethylcyclohex-2-enone 
• 13856-85-4 1-(4-chlorophenyl)-1-propanol 
• 1040402-96-7 (S)-1-(4-chlorophenyl)allyl acetate 
• 1362084-89-6 (R)-1-(4-chlorophenyl)allyl acetate 
• 956-02-5 4'-chlorochalcone 
• 5739-37-7 4'-chloro-3-phenylpropiophenone 

Relevant articles and documents

Microwave-Assisted 1,3-Dioxa-[3,3]-Sigmatropic Rearrangement of Substituted Allylic Carbamates: Application to the Synthesis of Novel 1,3-Oxazine-2,4-dione Derivatives

In a first instance, the effect of the microwave irradiation on the 1,3-Dioxa-[3,3]-sigmatropic rearrangement of aryl allylic carbamates was investigated. Under these new conditions, the reaction acceleration was clearly highlighted compared to convention

Iridium-Catalyzed Asymmetric Allylic Alkylation of Deconjugated Butyrolactams

Compared with the ever-growing list of nonprochiral nucleophiles in Ir-catalyzed asymmetric allylic substitution reactions, prochiral nucleophiles are less studied. We present a new prochiral nucleophile, namely, deconjugated butyrolactam, for Ir-catalyze

Enantioselective Allylation of Alkenyl Boronates Promotes a 1,2-Metalate Rearrangement with 1,3-Diastereocontrol

Alkenyl boronates add to Ir(π-allyl) intermediates with high enantioselectivity. A 1,2-metalate shift forms a second C-C bond and sets a 1,3-stereochemical relationship. The three-component coupling provides tertiary boronic esters that can undergo multiple additional functionalizations. An extension to trisubstituted olefins sets three contiguous stereocenters.