105705-43-9

Upstream product

• 124-38-9 carbon dioxide 
• 105705-41-7 1-(2-bromo-3,5-dimethoxyphenyl)-3,3-diethoxypentane 
• 616-25-1 1-Penten-3-ol 
• 91-52-1 2,4 dimethoxybenzoic acid 
• 105705-33-7 diethyl 2-(2-bromo-3,5-dimethoxybenzyl)propane-1,3-dione 
• 105705-35-9 2-(2-bromo-3,5-dimethoxybenzyl)propane-1,3-dioic acid 
• 105705-39-3 1-(2-bromo-3,5-dimethoxyphenyl)pentan-3-one 
• 105705-37-1 3-(2-bromo-3,5-dimethoxyphenyl)propanoic acid 
• 105705-19-9 3-(2-Bromo-3,5-dimethoxy-phenyl)-propionyl chloride 
• 105705-31-5 2-bromo-3,5-dimethoxybenzyl chloride 

Downstream Products

• 35578-70-2 miriquidic acid 
• 105705-18-8 benzyl miriquidate 
• 35583-00-7 2-hydroxy-4-methoxy-6-(3-oxopentyl)benzoic acid 

Relevant academic research and scientific papers

Ruthenium-Catalyzed C-H Functionalization of Benzoic Acids with Allyl Alcohols: A Controlled Reactivity Switch between C-H Alkenylation and C-H Alkylation Pathways

A highly selective and switchable ruthenium-catalyzed ortho C-H alkylation and C-H alkenylation of benzoic acids with allyl alcohols is reported. A complete switch in selectivity is achieved upon tuning the reactivity of the organometallic intermediate in the carboxylate-directed C-H activation to provide access to highly useful motifs such as 2-alkylbenzoic acids and phthalides.

Synthesis of the Lichen Depsides Miriquidic Acid and Normiriquidic Acid

The total synthesis of the lichen depsides miriquidic acid (1) and normiriquidic acid (2) is reported.The latter depside has been shown to co-occur with miriquidic acid in the lichen Lecidea leucophaea (Flk.) Nyl. by chromatographic comparisons.