105938-06-5Relevant academic research and scientific papers
Formation of C-Glycosides by Polarity Inversion at the Anomeric Centre
Hanessian, S.,Martin, M.,Desai, R. C.
, p. 926 - 927 (1986)
Alkylation of 1-lithio trisubstituted glycals obtained via the corresponding 1-tributylstannyl derivatives constitutes a novel entry into C-glycosides.
PREPARATION AND USE OF LITHIATED GLYCALS: VINYLIC DEPROTONATION VERSUS TIN-LITHIUM EXCHANGE FROM 1-TRIBUTYLSTANNYL GLYCALS
Lesimple, Patrick,Beau, Jean-Marie,Jaurand, Guy,Sinay, Pierre
, p. 6201 - 6204 (2007/10/02)
Methods for preparing glycals lithiated at the C-1 atom by either direct vinylic deprotonation or by tin-lithium exchange from the corresponding 1-tri-n-butylstannyl glycals are described.Alkylation of these lithiated anions wih various electrophiles lead
