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105993-90-6

Benzene, (2-chloro-1-fluoroethenyl)-, (E)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 105993-90-6 Structure

  • Basic information

    1. Product Name: Benzene, (2-chloro-1-fluoroethenyl)-, (E)-
    2. Synonyms:
    3. CAS NO:105993-90-6
    4. Molecular Formula: C8H6ClF
    5. Molecular Weight: 156.587
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 105993-90-6.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Benzene, (2-chloro-1-fluoroethenyl)-, (E)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Benzene, (2-chloro-1-fluoroethenyl)-, (E)-(105993-90-6)
    11. EPA Substance Registry System: Benzene, (2-chloro-1-fluoroethenyl)-, (E)-(105993-90-6)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 105993-90-6(Hazardous Substances Data)

105993-90-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 105993-90-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,5,9,9 and 3 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 105993-90:
(8*1)+(7*0)+(6*5)+(5*9)+(4*9)+(3*3)+(2*9)+(1*0)=146
146 % 10 = 6
So 105993-90-6 is a valid CAS Registry Number.

105993-90-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name chloro-2 fluoro-1 phenyle-1 ethylene (E)

1.2 Other means of identification

Product number -
Other names ((E)-2-Chloro-1-fluoro-vinyl)-benzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:105993-90-6 SDS

105993-90-6Relevant articles and documents

Stereodivergent Alkyne Hydrofluorination Using Protic Tetrafluoroborates as Tunable Reagents

Geaneotes, Paul,Guo, Rui,Liu, Peng,Qi, Xiaotian,Wang, Ruihan,Wang, Yi-Ming,Xiang, Hengye

, p. 16651 - 16660 (2020)

The discovery of safe, general, and practical procedures to prepare vinyl fluorides from readily available precursors remains a synthetic challenge. The metal-free hydrofluorination of alkynes constitutes an attractive though elusive strategy for their preparation. Introduced here is an inexpensive and easily handled reagent that enables the development of simple and scalable protocols for the regioselective hydrofluorination of alkynes to access both the E and Z isomers of vinyl fluorides. These reaction conditions were suitable for a diverse collection of alkynes, including several highly functionalized pharmaceutical derivatives. Computational and experimental mechanistic studies support C?F bond formation through vinyl cation intermediates, with the E- and Z-hydrofluorination products forming under kinetic and thermodynamic control, respectively.

Solvent- A nd anion-dependent rearrangement of fluorinated carbene ligands provides access to fluorinated alkenes

Hall, Lewis M.,Milner, Lucy M.,Hart, Sam J.,Whitwood, Adrian C.,Lynam, Jason M.,Slattery, John M.

supporting information, p. 17655 - 17659 (2019/12/23)

The construction of fluorocarbene ligands within the coordination sphere of transition metal complexes using sequential nucleophilic and electrophilic addition to a vinylidene complex is described. Reaction of [Ru(η5-C5H5)(dppe)(CCPhF)][N(SO2Ph)2] with [NMe4]F results in nucleophilic attack of fluoride at the metal-bound carbon of the vinylidene ligand to give alkenyl complex [Ru(η5-C5H5)(dppe)(-CFCFPh)]. Subsequent eletrophilic fluorination with N-fluorobenzenesulfonimide (NFSI) results in the formation of the fluorinated carbene complex [Ru(η5-C5H5)(dppe)(CF-CHFPh)][N(SO2Ph)2]. The fluorocarbene complexes undergo rearrangement to liberate free fluorinated alkenes, a process governed by the choice of solvent and anion, representing a new metal-mediated route to fluorinated alkenes from alkynes.

SYNTHESE DE CHLOROFLUOROVINYLSILANES ET DE QUELQUES DERIVES

Martin, Sophie,Sauvetre, Raymond,Normant, Jean-F.

, p. 317 - 320 (2007/10/02)

Several chlorofluoroolefins were prepared from 1,1-dichloro-2,2-difluoroethylene via chlorofluorovinylsilanes.

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