600121-19-5

Upstream product

• 106023-51-2 phenyl (5R)-4,6-O-benzylidene-1-seleno-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 600121-15-1 phenyl 2-O-benzyl-4,6-O-benzylidene-1-seleno-β-D-glucopyranoside 
• 600121-14-0 phenyl 3-O-acetyl-2-O-benzyl-4,6-benzylidene-1-seleno-β-D-glucopyranoside 

Relevant academic research and scientific papers

Efficient one-step synthesis of 2-hydroxy and 2-aminoglycals from selenoglycosides

2-Hydroxy and 2-aminoglycals are readily synthesised in one step from selenoglycosides by a Sharpless-type oxidation, which is then followed by spontaneous selenoxide elimination.

Elimination reactions of glycosyl selenoxides

Glycosyl selenoxides, generated in situ from selenoglycosides by a Sharpless-type oxidation, undergo facile syn elimination leading to 2-hydroxy and 2-amino glycals in high yield. Graphical abstract.