106046-60-0Relevant academic research and scientific papers
Dynamic kinetic resolution with enantioselective borohydride reduction catalyzed by optically active β-ketoiminato cobalt(II) complexes: Highly diastereo- and enantioselective preparation of optically active anti-aldol compounds
Ohtsuka, Yuhki,Miyazaki, Daichi,Ikeno, Taketo,Yamada, Tohru
, p. 24 - 25 (2002)
Optically active anti-2-alkyl-3-hydroxy esters were stereo-selectively obtained from the corresponding 2-alkyl-3-keto esters using enantioselective borohydride reduction along with dynamic kinetic resolution in the presence of optically active β-ketoimina
Synthesis, structure, and catalytic activity of palladium complexes bearing a tridentate PXP-pincer ligand of heavier group 14 element (X = Ge, Sn)
Takaya, Jun,Nakamura, Shuhei,Iwasawa, Nobuharu
supporting information, p. 967 - 969 (2012/11/07)
An efficient method for the synthesis of tridentate PGeP- and PSnP-palladium complexes is developed. Structural analysis revealed that PSiP-ligand exerts the strongest trans influence and electron donation and that PGeP- and PSnP-ligands provide wider coordination sphere around the palladium. Preliminary studies demonstrated that both PGeP- and PSnP-palladium complexes work as an efficient catalyst for reductive aldol-type reaction, indicating promising utility in synthetic organic chemistry.
Cp2ZrCl2-induced Reformatsky and Barbier reactions on isatins: An efficient synthesis of 3-substituted-3-hydroxyindolin-2-ones
Chouhan, Mangilal,Sharma, Ratnesh,Nair, Vipin A.
experimental part, p. 470 - 475 (2012/02/01)
A mild and rapid one-pot process for Reformatsky and Barbier reactions using a catalytic quantity of zirconocene dichloride (Cp2ZrCl 2) as a promoter and zinc as a terminal reductant at room temperature in dimethyl formamide was developed. The protocol has wide substrate suitability and afforded the desired 3-substituted-3-hydroxyindolin-2-ones from istains in good yields and short reaction time.
