106052-83-9Relevant academic research and scientific papers
The LiClO4-mediated synthesis of β-(dialkylamino) sulfoxides and β- (dialkylamino) sulfones by addition of α-lithiated salts of sulfoxides and sulfones to aldehydes and (trimethylsilyl)dialkylamines
Naimi-Jamal, M. Reza,Ipaktschi, Junes,Saidi, Mohammad R.
, p. 1735 - 1739 (2007/10/03)
The LiClO4-mediated one-pot reaction of aldehydes with (trimethylsilyl)dialkyl amines and the lithium salt of sulfoxides or sulfones, affords the corresponding β-(dialkylamino) sulfoxides and β- (dialkylamino) sulfones in high yields. The aminosulfoxidation reaction of aliphatic or aromatic aldehydes lacks diastereoselectivity, but the diastereomeric sulfoxides can be separated by HPLC or column chromatography for further use.
STEREOCHEMISTRY OF ORGANIC SULFUR COMPOUNDS. PART 20. CONFORMATIONAL ANALYSIS OF AMINOSULFOXIDES AND SULFONES
Brunet, E.,Gallego, M. T.,Ruano, J. L. Garcia,Alcudia, F.
, p. 1423 - 1438 (2007/10/02)
Synthesis and conformational analysis of 1-phenyl-2-methylsulfinyl (and -sulfonyl-) ethylamine (and its N-methyl and N,N-dimethylderivatives) are reported.Conformational preferences have been determined by carefully observing the changes of the vicinal co
