106221-07-2

Basic information

• Product Name: (R)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-prop-2-en-1-ol
• Synonyms: (R)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-prop-2-en-1-ol
• CAS NO: 106221-07-2
• Molecular Weight: 306.359
• Mol File: 106221-07-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-prop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-prop-2-en-1-ol(106221-07-2)
• EPA Substance Registry System: (R)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-prop-2-en-1-ol(106221-07-2)

Safety Data

• Hazardous Substances Data: 106221-07-2(Hazardous Substances Data)

Upstream product

• 1826-67-1 vinyl magnesium bromide 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 106221-02-7 [(Z)-3-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-allyl]-trimethyl-silane 

Downstream Products

• 1351932-60-9 C₂₇H₃₃NO₇ 
• 1351932-59-6 C₂₀H₂₅NO₆ 
• 1351932-58-5 C₂₇H₃₃NO₇ 
• 1351932-49-4 C₂₇H₃₃NO₇ 
• 1351932-57-4 C₁₉H₂₃NO₅ 
• 1351932-48-3 C₁₉H₂₃NO₅ 
• 906077-08-5 C₂₇H₃₃NO₇ 
• 18006-25-2 3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose diacetate 

Relevant articles and documents

A straightforward approach towards glycoamino acids and glycopeptides via Pd-catalysed allylic alkylation

Chelated enolates are versatile nucleophiles for palladium-catalysed allylic alkylations. Even with complex allylic substrates the reaction proceed without significant isomerisation. This allows the stereoselective introduction of polyhydroxylated allylic sidechains into amino acids and peptides with retention of the olefin geometry.

ON THE COMMUNICATION OF CHIRALITY FROM FURANOSE AND PYRANOSE RINGS TO MONOSACCHARIDE SIDE CHAINS: ANOMALOUS RESULTS IN THE GLUCOSE SERIES

The reactions of allyltrimethylsilane with dialdose derivatives occur, under catalysis by boron trifluoride etherate or titanium tetrachloride, with high stereoselectivity, thereby providing simple routes to the corresponding allyl carbinols.The sense of