18006-25-2

Basic information

• Product Name: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose
• Synonyms: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isoproylidene-a-D-glucofuranose;3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-α-D-glucofuranose;Nsc67057;1,2-O-(1-Methylethylidene)-3-O-(phenylMethyl)-α-D-glucofuranose Diacetate
• CAS NO: 18006-25-2
• Molecular Formula: C₂₀H₂₆O₈
• Molecular Weight: 0
• Product Categories: 13C & 2H Sugars;Carbohydrates & Derivatives
• Mol File: 18006-25-2.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 480.2°C at 760 mmHg
• Flash Point: 208°C
• Appearance: /
• Density: 1.25g/cm³
• Vapor Pressure: 2.22E-09mmHg at 25°C
• Refractive Index: 1.533
• CAS DataBase Reference: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose(18006-25-2)
• EPA Substance Registry System: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose(18006-25-2)

Safety Data

• Hazardous Substances Data: 18006-25-2(Hazardous Substances Data)

Usage

General Description

3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose is a complex chemical compound that belongs to the class of glucofuranose derivatives. It consists of a benzyl group attached to the 3-O position, acetyl groups attached to the 5 and 6-O positions, and an isopropylidene group at the 1 and 2-O positions of the glucopyranose ring. 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose is commonly used in organic synthesis and pharmaceutical research due to its unique structure and reactivity. It can serve as a building block for the synthesis of more complex molecules and can also be used as a protecting group for hydroxyl functional groups in carbohydrate chemistry. Overall, 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose is a versatile compound with diverse applications in chemical and pharmaceutical industries.

InChI:InChI=1/C20H26O8/c1-12(21)23-11-15(25-13(2)22)16-17(24-10-14-8-6-5-7-9-14)18-19(26-16)28-20(3,4)27-18/h5-9,15-19H,10-11H2,1-4H3

Upstream product

• 64656-76-4 Natrium-Verbindung der O¹,O²;O⁵,O⁶-Diisopropyliden-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 50-99-7 D-glucose 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 106221-07-2 (R)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-prop-2-en-1-ol 
• 106221-02-7 [(Z)-3-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-allyl]-trimethyl-silane 
• 106221-10-7 Acetic acid (R)-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-but-3-enyl ester 
• 108-24-7 acetic anhydride 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 18549-40-1 1,2-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 18006-29-6 O⁶-benzoyl-O³-benzyl-O¹,O²-isopropylidene-O⁵-(toluene-4-sulfonyl)-α-D-glucofuranose 
• 22331-18-6 O³-benzyl-O¹,O²-isopropylidene-O⁵,O⁶-bis-(toluene-4-sulfonyl)-α-D-glucofuranose 
• 35781-78-3 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 1218918-94-5 acetic acid (1R,2R,3R,4S,5S)-2-acetoxy-1-(5-allyl-3-benzyloxy-4-hydroxy-tetrahydrofuran-2-yl)-ethyl ester 
• 42926-89-6 1,2-O-isopropylidene-3-O-benzyl-α-D-glucofuranose 
• 781657-62-3 phenyl 2,4,6-tri-O-acetyl-1-thio-α/β-L-idopyranose 
• 781657-65-6 Acetic acid (2R,4aS,7R,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 781657-64-5 (2R,4aS,7R,8R,8aR)-8-Benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 781657-63-4 phenyl 3-O-benzyl-1-thio-L-idopyranoside 
• 37776-17-3 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-β-L-idofuranose 
• 118711-49-2 1,2,4,6-tetra-O-acetyl-3-O-benzyl-L-idopyranoside 
• 84563-90-6 6-O-acetyl-3-O-benzyl-1,2-O-isopropylidene-5-O-methanesulfonyl-α-D-glucofuranose 
• 5531-09-9 3-O-benzyl-L-idopyranose 
• 22331-19-7 3-O-benzyl-1,2-O-isopropylidene-5,6-di-O-mesyl-α-D-glucofuranose 

Relevant articles and documents

SYNTHESIS OF SOME L-IDOSE DERIVATIVES

The synthesis of 3-O-benzyl and 3-O-mesyl-1,2-O-isopropylidene-β-L-idofuranose has been effected on the basis of the intramolecular nucleophilic exchange of a mesyloxy group at C5 in derivatives of 1,2-O-isopropylidene-α-D-glucofuranose.It has

ON THE COMMUNICATION OF CHIRALITY FROM FURANOSE AND PYRANOSE RINGS TO MONOSACCHARIDE SIDE CHAINS: ANOMALOUS RESULTS IN THE GLUCOSE SERIES

The reactions of allyltrimethylsilane with dialdose derivatives occur, under catalysis by boron trifluoride etherate or titanium tetrachloride, with high stereoselectivity, thereby providing simple routes to the corresponding allyl carbinols.The sense of