106260-08-6

Basic information

• Product Name: 2-Butenoic acid, 4,4,4-trifluoro-3-hydroxy-, ethyl ester, (Z)-
• CAS NO: 106260-08-6
• Molecular Formula: C6H7F3O3
• Molecular Weight: 184.115
• Mol File: 106260-08-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Butenoic acid, 4,4,4-trifluoro-3-hydroxy-, ethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 4,4,4-trifluoro-3-hydroxy-, ethyl ester, (Z)-(106260-08-6)
• EPA Substance Registry System: 2-Butenoic acid, 4,4,4-trifluoro-3-hydroxy-, ethyl ester, (Z)-(106260-08-6)

Safety Data

• Hazardous Substances Data: 106260-08-6(Hazardous Substances Data)

Upstream product

• 197850-97-8 Aethyl-γ,γ,γ-trifluoracetoacetat-hydrat 

Downstream Products

• 571-55-1 ethyl 2-(ethoxymethylidene)-4,4,4-trifluoro-3-oxobutanoate 
• 197850-97-8 Aethyl-γ,γ,γ-trifluoracetoacetat-hydrat 
• 372-31-6 ethyl 4,4,4-trifluoroacetoacetate 
• 16626-70-3 N_.N'-Bis-(4-methoxy-phenyl)-formazylameisensaeureethylester 
• 138536-04-6 5-Hydroxy-2-methyl-3-phenyl-5-trifluoromethyl-isoxazolidine-4-carboxylic acid ethyl ester 

Relevant articles and documents

Inversion of enantioselectivity during the platinum-catalyzed hydrogenation of an activated ketone

Two competing reaction pathways, which lead to opposite enantiomers (see scheme), occur in the hydrogenation of 1 over chirally modified platinum, as revealed by catalytic and NMR spectroscopic experiments: the fast reduction of the ketoform 1a (minor species) and the slow hydrogenolysis of the hydrate 3 (major species).