111380-75-7

Upstream product

• 50-00-0 formaldehyd 
• 101241-21-8 3a,6a-diphenylglycoluril 

Downstream Products

• 1201680-66-1 C₃₄H₂₆N₈O₄ 
• 1258046-77-3 C₃₆H₂₆N₈O₆ 
• 1352409-24-5 1,3,4,6-tetrakis[(acetyloxy)methyl]tetrahydro-3a,6a-diphenyl-imidazo[4,5-d]imidazole-2,5(1H,3H)-dione 
• 1380508-64-4 34b,34c-diphenyl-2,3,5,6,8,9,11,12,15,17,20,21,23,24,26,27,29,30,33,34b,34c,35-docosahydro-1,4,7,10,13,19,22,25,28,31-decaoxa-15a,16a,33a,34a-tetraazacyclopentadeca[1',2':4,5]benzo[1,2-f]cyclopentadeca[1'',2'':4',5']benzo[1',2':5,6]azuleno[2,1,8-ija]azulene-16,34-dione 
• 1333429-14-3 C₅₂H₆₂N₄O₁₄ 
• 1380508-66-6 C₆₀H₇₈N₄O₁₈ 
• 1380508-65-5 C₅₆H₇₀N₄O₁₆ 
• 106319-02-2 1,3:4,6-Bis(1,4-dihydroxy-2,3-xylylene)tetrahydro-3a,6a-diphenylimidazo<4,5-d>imidazole-2,5(1H,3H)-dione 

Relevant academic research and scientific papers

Synthesis and crystal structure of a novel molecular clip from diphenylglycoluril and phthalhydrazide

A novel molecular clip from diphenylglycoluril and phthalhydrazide has been synthesised. Its structure and conformation was confirmed by single crystal X-ray diffraction.

Glycoluril-tetrathiafulvalene molecular clips: On the influence of electronic and spatial properties for binding neutral accepting guests

Glycoluril-based molecular clips incorporating tetrathiafulvalene (TTF) sidewalls have been synthesized through different strategies with the aim of investigating the effect of electrochemical and spatial properties for binding neutral accepting guests. W

A molecular chalice with hydrophobic walls and a hydrophilic rim: Self-assembly and complexation properties

We describe the synthesis of a diphenylglycoluril/dibenzo-crown-6 molecular chalice, the self-assembly at the air/water interface and its complexation properties in solution and at the water/chloroform interface.

Synthesis and X-ray structure of new molecular clips based on diphenylglycoluril

A pair of new molecular clips based on diphenylglycoluril and 1, 2-dihydroindazol-3-one have been synthesised. Their structures and conformations were confirmed by single crystal X-ray diffraction.

METHOD FOR PREPARING COMPOUNDS COMPRISING CUCURBITURIL GROUPS

The present invention provides a method for preparing compounds comprising a plurality of cucurbituril groups. The method comprises forming a mixture comprising one or more compounds of the formula A-L-A wherein L is a linking group and A is group of the

Palladium(II) Cage Compounds Based on Diphenylglycoluril

A four-armed tetra-1-imidazolyl ligand (Lig) equipped with the concave framework of diphenylglycoluril (tetrahydro-3a,6a-diphenylimidazoimidazole-2,5(1H,3H)-dione) has been designed to construct a host that contains a potentially catalytically active metal center in or close to a cavity.Reaction of Lig (arm = CH2(OCH2CH2)2Im) with Pd(CH3CN)2Cl2 results in the formation of a complex with the general formula Cl2.This complex has a cage structure that is unstable and collapses.The collapsed structure has either a left or a right twisted conformation.These conformations interconvert rapidly, the activation free energy of the process being 30 +/- 2 kJ.mol-1.Ligands without oxygen atoms or only one oxygen atom per arm react with Pd(CH3CN)2Cl2 to afford cage complexes with the molecular formula Cl.The cages of these complexes do not collapse.The imidazolyl groups and the chloride ions are involved in a scrambling process in such a way that at any moment the Pd2+ ion is surrounded by three imidazolyl groups and one chloride ion.Data are presented suggesting that intramolecular H bonding is a driving force for cage collapse.