106353-49-5

Basic information

• Product Name: 2-Hexanone, 4-hydroxy-6-phenyl-, (R)-
• CAS NO: 106353-49-5
• Molecular Formula: C12H16O2
• Molecular Weight: 192.258
• Mol File: 106353-49-5.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 2-Hexanone, 4-hydroxy-6-phenyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexanone, 4-hydroxy-6-phenyl-, (R)-(106353-49-5)
• EPA Substance Registry System: 2-Hexanone, 4-hydroxy-6-phenyl-, (R)-(106353-49-5)

Safety Data

• Hazardous Substances Data: 106353-49-5(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 66536-78-5 (+)-(R)-1-(p-tolylsulfinyl)-2-propanone 
• 14583-98-3 1-tributylstannanyl-propan-2-one 
• 67-64-1 acetone 
• 33046-41-2 (E)-6-phenyl-3-hexen-2-one 
• 31874-34-7 (E)-2,4-dimethoxybenzaldehyde oxime 
• 116-11-0 2-Methoxypropene 

Relevant articles and documents

Direct asymmetric aldol reactions of acetone using bimetallic zinc catalysts

(Equation presented) The enantioselective aldol reaction using a novel binuclear zinc catalyst of acetone with several aldehydes gave products in good yields (62-89%) with a high level of enantioselectivity (ee = 76-92%).

To probe the origin of activation effect of carboxylic acid and (+)-NLE in tridentated titanium catalyst systems

The activation effect of carboxylic acid and positive nonlinear effect ((+)-NLE) in tridentated titanium catalyst systems for hetero Diels-Alder reaction and aldol-type reactions has been first elucidated on the basis of X-ray crystal structural analysis

Improved conditions for the proline-catalyzed aldol reaction of acetone with aliphatic aldehydes

The proline-catalyzed asymmetric aldol reaction between aliphatic aldehydes and acetone has, to date, remained underdeveloped. Challenges in controlling this reaction include avoiding undesired side reactions such as aldol condensation and self-aldolization. In recent years we have developed optimized conditions, which enable high yields and good to excellent enantioselectivities, and which are presented in this communication. Georg Thieme Verlag Stuttgart New York.

Catalytic asymmetric hydroperoxidation of α,β-unsaturated ketones: An approach to enantiopure peroxyhemiketals, epoxides, and aldols

(Chemical Equation Presented) Efficient, selective: The primary amine salt 1 derived from quinine efficiently catalyzes the highly enantioselective hydroperoxidation of α,β-unsaturated ketones furnishing stable and isolable cyclic peroxyhemiketals in enan