106367-31-1

Upstream product

• 4301-07-9 β-Chlor-pivalophenon 
• 100-46-9 benzylamine 
• 4298-69-5 β-p-Tosyloxy-α,α-dimethyl-propiophenon; β-p-Tosyloxy-pivalophenon 
• 56010-63-0 2,2-dimethyl-3-hydroxy-1-phenylpropan-1-one 
• 611-70-1 phenyl isopropyl ketone 

Downstream Products

• 50407-04-0 α-Methoxy-β,β-dimethylstyrol 
• 119639-99-5 Benzyl-(3,3-dimethoxy-2,2-dimethyl-3-phenyl-propyl)-amine 
• 123445-53-4 (+/-)-2,2-dimethyl-1-aminocyclopropane-1-carboxylic acid 
• 128419-49-8 N-(2,2-dimethyl-1-phenyl-1-cyclopropyl)trifluoroacetamide 
• 938-16-9 2,2-dimethylpropiophenone 
• 109296-40-4 2,2-dimethyl-1-phenylcyclopropylamine 
• 110871-26-6 2,2-dimethyl-3-(N-benzylamino)-1-phenyl-1-propanone 
• 611-70-1 phenyl isopropyl ketone 
• 109296-31-3 N-(benzylidene)-2,2-dimethyl-1-phenylcyclopropylamine 
• 99315-31-8 1-Benzyl-3,3-dimethyl-2-phenyl-azetidine-2-carbonitrile 

Relevant academic research and scientific papers

SYNTHESIS OF 2,2-DIMETHYL-1-AMINOCYCLOPROPANECARBOXYLIC ACID FROM β-CHLOROIMINES

2,2-Dimethyl-ACC, a potential plant growth regulator, was synthesized by cyclopropanation of β-chloroimines.

SYNTHESIS OF AZETIDINES FROM β-CHLORO IMINES

The reaction of β-chloro imines 4 with potassium cyanide in methanol or with lithium aluminium hydride in dry ether gave rise to 2-cyanoazetidines 5 and azetidines 21.The reaction proceeded by nucleophilic addition of cyanide or hydride across the carbon-

Synthesis of β-Chloroimines

β-Chloroimines 6 have been prepared from β-chlorocarbonyl compounds 5 by reaction with primary amines via two major approaches.