106445-05-0

Upstream product

• 106445-04-9 1-(6-benzyloxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(tert-butyldimethylsiloxy)ethanol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 

Downstream Products

• 121403-54-1 (R)-2-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-1-(tert-butyl-dimethyl-silanyloxy)-3-nitro-propan-2-ol 
• 121403-54-1 (S)-2-((3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-1-(tert-butyl-dimethyl-silanyloxy)-3-nitro-propan-2-ol 
• 106445-06-1 methyl 3-O-benzyl-5-C-tert-butyldimethylsilyloxymethyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hept-5-(Z)-enofuranosyluronate 
• 114244-52-9 3-O-benzyl-6-O-(tert-butyldimethylsilyl)-5-deoxy-1,2-O-isopropylidene-5-C-methylene-α-D-xylo-hexofuranose 
• 208174-51-0 (3aR,5S,6S,6aR)-6-Benzyloxy-5-[(Z)-2-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-vinyl]-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 104331-52-4 3-O-benzyl-6-deoxy-5-C-ethyl-1,2-O-isopropylidene-5-O-methyl-α-D-glucofuranose 
• 148236-82-2 (3aR,5S,6S,6aR)-6-Benzyloxy-5-((S)-1-methoxy-1-methyl-allyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 148236-81-1 (3aR,5S,6S,6aR)-6-Benzyloxy-2,2-dimethyl-5-((R)-2-vinyl-oxiranyl)-tetrahydro-furo[2,3-d][1,3]dioxole 
• 148236-85-5 (R)-4-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-4-benzyloxymethyl-oxazolidin-2-one 
• 148236-87-7 Benzoic acid (3aR,3bS,6S,6aR,7aR)-6-benzoylamino-2,2-dimethyl-5-oxo-hexahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxol-6-ylmethyl ester 
• 148236-83-3 4-(3-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranos-5-yl)-3-(4-methoxyphenyl)-4-vinyloxazolidin-2-one 
• 148236-84-4 (R)-4-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-4-benzyloxymethyl-3-(4-methoxy-phenyl)-oxazolidin-2-one 

Relevant academic research and scientific papers

Highly stereoselective indium trichloride-catalysed asymmetric aldol reaction of formaldehyde and a glucose-derived silyl enol ether in water

The yield and stereochemical outcome of the reaction between D-glucose-derived silyl enol ether 1 (Z and E isomers) and commercial formaldehyde in water catalysed by indium(III) choride was studied.

Zaragozic acid a : Interesting observations in anhydro-ring formation of densely functionalised carbohydrate templates

A methodology which produced highly substituted 1,6-anhydrofuranose derivative, symbolising 2,8-dioxobicyclo[3.2.1]octan core of zaragozic acid, has been described.

A formal synthesis of a novel immunosuppressant ISP-1 : Stereocontrolled Pd(O) catalysedcis-hydroxyamination of carbohydrate derived vinyl epoxide

Described herein are the results leading to the synthesis of ISP-1 containing an unusal α, α-disubstituted amino acid and whose immunosuppressive activity only has recently been discovered.

SYNTHESES OF PSEUDO-α-D-GLUCOPYRANOSE AND PSEUDO-β-L-IDOPYRANOSE, TWO OPTICALLY ACTIVE PSEUDO-HEXOPYRANOSES, FROM D-GLUCOSE BY USING STEREOSELECTIVE REDUCTIVE DEACETOXYLATION WITH SODIUM BOROHYDRIDE AND CYCLITOL FORMATION FROM NITROFURANOSE AS KEY REACTIO

Two optically active pseudo-hexopyranoses, pseudo-α-D-glucopyranose and pseudo-β-L-idopyranose, have been synthesized from D-glucose by using stereoselective deacetoxylations with NaBH4 and cyclitol formations from nitrofuranose derivatives as key reactio

1,3,5-TRIDEOXY-3,5-DI-C-METHYL-L-TALITOL: A CHIRON FOR THE C-33-C-37 SEGMENT OF AMPHOTERICIN B

1,3,5-Trideoxy-3,5-di-C-methyl-L-talitol is a potential chiron for the C-33-C-37 segment of amphotericin B.This hexitol has been synthesized from 3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose by a route in which a C-methylene derivative at C-5 is hydr