106450-03-7Relevant academic research and scientific papers
Immobilized Co/Rh heterobimetallic nanoparticle-catalyzed Pauson-Khand-type reaction
Kang, Hyun Park,Young, Keun Chung
, p. 854 - 866 (2005)
Co/Rh heterobimetallic nanoparticles were prepared from cobalt-rhodium carbonyl clusters [Co2Rh2(CO)12 and Co 3Rh(CO)12] and immobilized on charcoal. HR-TEM revealed that the size of the heterobimetal
Microwave promoted Pauson-Khand reactions
Iqbal, Mazhar,Vyse, Nicola,Dauvergne, Jér?me,Evans, Paul
, p. 7859 - 7862 (2002)
The synthesis of various cyclopentenones via the Pauson-Khand reaction, employing for the first time microwave energy to initiate this cycloaddition process is reported.
REACTIONS OF CIS-SILYL TIN OLEFINS: (ANTI-DENMARK) NAZAROV CYCLIZATION OF β-SILYL DIVINYL KETONES
Chenard, B. L.,Zyl, C. M. Van,Sanderson, D. R.
, p. 2801 - 2804 (2007/10/02)
Readily available silyl tin olefins efficiently couple with acid chlorides (Stille Reaction) to give β-silyl divinyl ketones.These ketones with large silyl groups (Et3Si, t-BuMe2Si) undergo Nazarov cyclizations wherein the silicon group is retained in the
