106470-35-3Relevant academic research and scientific papers
Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides
Noble, Adam,McCarver, Stefan J.,Macmillan, David W. C.
, p. 624 - 627 (2015)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple hydrocarbon-substituted acids. Diverse vinyl iodides and bromides give rise to vinylation products in high efficiency under mild, operationally simple reaction conditions.
Cross-Coupling Reactions of Alkenyl Halides with 4-Benzyl-1,4- Dihydropyridines Associated with E to Z Isomerization under Nickel and Photoredox Catalysis
Nakajima, Kazunari,Guo, Xifeng,Nishibayashi, Yoshiaki
supporting information, p. 3653 - 3657 (2018/11/10)
Cross-coupling reactions of alkenyl halides with 4-alkyl-1,4-dihydropyridines as alkylation reagents have been achieved by combination of nickel and photoredox catalysts. Alkenyl halides bearing alkyl and aryl substituents are available. Particularly, in
Cross-coupling reaction of allylic and benzylic carbonates with organo[2-(hydroxymethyl)phenyl]dimethylsilanes
Nakao, Yoshiaki,Ebata, Shiro,Chen, Jinshui,Imanaka, Hidekazu,Hiyama, Tamejiro
, p. 606 - 607 (2008/02/07)
The title reaction is found to proceed in the presence of a palladium catalyst and in the absence of any activator. Various functional groups are tolerated to give a diverse range of 1,4-diene and diarylmethane products, which are ubiquitous units of natural products and pharmaceuticals. Copyright
A Total Synthesis of the Methyl Ester of the 9,11-Dithia Analogue of 13,14-Dehydro-PGH2
Ghosh, Soumitra S.,Martin, John C.,Fried, Josef
, p. 862 - 876 (2007/10/02)
A total synthesis of the disulfide analogue 2 of 13,14-dehydro-PGH2 methyl ester is described.A key intermediate is the mesylate of the 3-phenyl-2,4-dithiabicyclooctane derivative 37b, which undergoes alkynylation via an episulfonium intermediate t
