42599-17-7

Basic information

• Product Name: trans-1-Iodo-1-octene
• Synonyms: trans-1-Iodo-1-octene;trans-1-Iodo-1-octene >=95.0% (GC);1(E)-Iodo-oct-1-ene
• CAS NO: 42599-17-7
• Molecular Formula: C₈H₁₅I
• Molecular Weight: 238.10917
• Mol File: 42599-17-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 189.76°C (estimate)
• Appearance: /
• Density: 1.3204 (rough estimate)
• Refractive Index: n20/D1.502
• BRN: 2346520
• CAS DataBase Reference: trans-1-Iodo-1-octene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1-Iodo-1-octene(42599-17-7)
• EPA Substance Registry System: trans-1-Iodo-1-octene(42599-17-7)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-51/53
• Safety Statements: 61
• RIDADR: UN 3082 9 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 42599-17-7(Hazardous Substances Data)

Usage

General Description

Trans-1-iodo-1-octene is a chemical compound with the molecular formula C8H15I. It is an organic compound that belongs to the class of alkenes, which are unsaturated hydrocarbons with at least one carbon-carbon double bond. This particular compound has a trans configuration, meaning that the iodine and the alkene functional group are on opposite sides of the double bond. Trans-1-iodo-1-octene is commonly used in organic synthesis and as a reagent in various chemical reactions due to the presence of the iodine atom, which can easily undergo substitution reactions. It is also used in the production of pharmaceuticals and agrochemicals, as well as in the manufacturing of dyes and perfumes. Additionally, it has applications in the field of materials science, serving as a precursor for the synthesis of polymers and other advanced materials.

Upstream product

• 629-05-0 n-octyne 
• 592-41-6 1-hexene 

Downstream Products

• 40856-16-4 (E)-non-2-enenitrile 
• 7206-16-8 (E)-dodec-5-ene 
• 162358-91-0 1-bromo-2-[(E)-oct-1-enyl]benzene 
• 111-66-0 oct-1-ene 
• 71686-99-2 (7E,9E)-hexadeca-7,9-diene 
• 174365-91-4 (1E,3E)-1-bromo-1,3-decadiene 
• 69530-71-8 (E)-benzyl(ooct-1-enyl)sulfane 
• 112033-09-7 ((E)-2-Oct-1-enyl)-cyclopentanone 
• 112033-18-8 2-<(E)-1-octenyl>cyclohexanone 
• 1000600-73-6 C₃₀H₄₄OSi 
• 28665-60-3 (E)-1-phenyl-1-octene 
• 693-62-9 undec-4-ene 
• 1140528-15-9 (1E,5E)-1-(4-methylphenyl)selenododeca-1,5-dien-3-yne 
• 1234892-57-9 (E,E)-1-(4-chlorophenyl)-1,2-diphenyl-1,3-decadiene 

Relevant articles and documents

Vinylic Organoboranes. 9. A General Stereospecific Synthesis of (Z)- and (E)-Disubstituted Alkenes via Organoboranes

A general and stereospecific synthesis of (Z)-disubstituted alkenes using mono- and dihaloboranes is presented.The hydridation of dialkylhaloboranes in the presence of 1-alkynes provides the corresponding dialkylvinylboranes (1), representing the first general synthesis of such derivatives.Treatment with iodine in the presence of sodium methoxide induces the migration of one of the alkyl groups from boron to the adjacent carbon, followed by a rapid deiodoboronation to afford (Z)-disubstituted alkenes (2) in high yields.Similarly, the hydroboration of 1-alkynes with alkyl bromoboranes (R1BHBr*SMe2, 4) followed by iodination in the presence of sodium methoxide in methanol affords (Z)-disubstituted alkenes (2) in good yields.Both procedures constitute a general one-pot synthesis of (Z)- disubstituted alkenes from an alkene and 1-alkyne.A simple synthesis of Muscalure (7), the sex pheromone of the housefly (Musca domestica), is achieved in good yields.An alternative general stereospecific synthesis of (Z)- and (E)-disubstituted alkenes based on alkenylboronic esters is also described.