106552-37-8

Basic information

• Product Name: (E)-3,3-diphenyl-1-(p-tolyl)prop-2-en-1-one
• Synonyms: (E)-3,3-diphenyl-1-(p-tolyl)prop-2-en-1-one
• CAS NO: 106552-37-8
• Molecular Weight: 298.384
• Mol File: 106552-37-8.mol

Chemical Properties

• CAS DataBase Reference: (E)-3,3-diphenyl-1-(p-tolyl)prop-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3,3-diphenyl-1-(p-tolyl)prop-2-en-1-one(106552-37-8)
• EPA Substance Registry System: (E)-3,3-diphenyl-1-(p-tolyl)prop-2-en-1-one(106552-37-8)

Safety Data

• Hazardous Substances Data: 106552-37-8(Hazardous Substances Data)

Upstream product

• 618-41-7 Benzenesulfinic acid 
• 4224-96-8 3-phenyl-1-p-tolylprop-2-en-1-one 
• 80676-77-3 1-(1-t-butyldimethylsiloxyethenyl)-4-methylbenzene 
• 530-48-3 1,1-Diphenylethylene 
• 874-60-2 4-methyl-benzoyl chloride 
• 104-87-0 4-methyl-benzaldehyde 
• 7664-93-9 sulfuric acid 
• 902-96-5 (1,1-diphenyl-3-p-tolyl-prop-2-ynyl)-methyl ether 
• 7647-01-0 hydrogenchloride 
• 1522-14-1 1,1-diphenyl-3-(p-tolyl)prop-2-yn-1-ol 
• 116245-96-6 5,5-Diphenyl-3,7-di-p-tolyl-5,6-dihydro-4H-[1,2]diazepine 
• 41501-68-2 3,3-dichloro-1-(4-tolyl)-2-propen-1-one 
• 98-80-6 phenylboronic acid 

Relevant articles and documents

Copper-catalyzed oxidative coupling of alkenes with aldehydes: Direct access to α,β-unsaturated ketones

Let's get radical: The first copper-catalyzed oxidative coupling of alkenes and aldehydes was developed. Various aldehydes were utilized as substrates to construct α,β-unsaturated ketones. A preliminary mechanistic study indicated that this reaction is likely to proceed through a single-electron transfer. Copyright

Functionalized β,β-dichloroenones and β,β-dibromoenones as versatile building blocks: Synthesis and transformations

An efficient one-step synthesis of functionalized β,β-dichloroenones and β,β-dibromoenones was achieved via the Fe-catalyzed radical induced reaction between silyl enol ethers and carbon tetrachloride, bromotrichloromethane or carbon tetrabromide in moderate to good yields. This reaction proceeds through addition of the trichloromethyl or tribromomethyl radical group to the C[dbnd]C bond of the silyl enol ethers and subsequent base-induced elimination under mild conditions.

Acylation of Alkenes with the Aid of AlCl3 and 2,6-Dibromopyridine

Friedel-Crafts-type acylation of alkenes with acyl chlorides has been successfully conducted with a wide substrate scope by the combined use of AlCl3 and 2,6-dibromopyridine. Trisubstituted alkenes afford allylketones or vinylketones depending on the presence or absence of hydrogen atom(s) at the β-position to the acylation site, while monosubstituted alkenes exclusively afford vinylketones.

β-Selective Aroylation of Activated Alkenes by Photoredox Catalysis

Late-stage synthesis of α,β-unsaturated aryl ketones remains an unmet challenge in organic synthesis. Reported herein is a photocatalytic non-chain-radical aroyl chlorination of alkenes by a 1,3-chlorine atom shift to form β-chloroketones as masked enones

Palladium-catalyzed desulfitative conjugate addition of aryl sulfinic acids and direct ESI-MS for mechanistic studies

A new and efficient method for palladium(II) catalytic desulfitative conjugate addition of arylsulfinic acids with α,β-unsaturated carbonyl compound has been developed. The key reacting intermediates including aryl Pd(II) sulfinic intermediate, aryl Pd(II), and C=O-Pd complexes were captured by ESI-MS/MS, which provide new experimental evidence for the understanding of addition mechanism.