106600-20-8

Basic information

• Product Name: 2,3,4,6-tetraacetate-1-(2-bromobenzoate) β-D-glucopyranose
• CAS NO: 106600-20-8
• Molecular Weight: 531.311
• Mol File: 106600-20-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetraacetate-1-(2-bromobenzoate) β-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetraacetate-1-(2-bromobenzoate) β-D-glucopyranose(106600-20-8)
• EPA Substance Registry System: 2,3,4,6-tetraacetate-1-(2-bromobenzoate) β-D-glucopyranose(106600-20-8)

Safety Data

• Hazardous Substances Data: 106600-20-8(Hazardous Substances Data)

Upstream product

• 19879-84-6 tetraacetyl thioglucose 
• 88-65-3 2-bromobenzoic-acid 

Relevant articles and documents

Reversing Reactivity: Stereoselective Desulfurative 1,2- trans- O-Glycosylation of Anomeric Thiosugars with Carboxylic Acids under Copper or Cobalt Catalysis

We have discovered a new mode of reactivity of 1-thiosugars in the presence of Cu(II) or Co(II) for a stereoselective O-glycosylation reaction. The process involves the use of a catalytic amount of Cu(acac)2 or Co(acac)2 and Ag2CO3 as an oxidant in α,α,α-trifluorotoluene. Moreover, this protocol turned out to have a broad scope, allowing the preparation of a wide range of complex substituted O-glycoside esters in good to excellent yields with an exclusive 1,2-trans-selectivity. The late-stage modification of pharmaceuticals by this method was also demonstrated. To obtain a closer insight into the reaction mechanism, cyclic voltammetry was performed.