106680-71-1

Upstream product

• 58719-77-0 2-O-benzyl-D-glucopyranose 
• 127753-63-3 (2R,3S,4S,5R,6R)-5-Benzyloxy-6-[((E)-buta-1,3-dienyl)oxy]-2-hydroxymethyl-tetrahydro-pyran-3,4-diol 
• 127753-74-6 (2R,3S,4S,5R,6S)-2-Benzyloxymethyl-6-[((E)-buta-1,3-dienyl)oxy]-tetrahydro-pyran-3,4,5-triol 
• 127753-64-4 (2R,3S,4S,5R,6S)-5-Benzyloxy-6-[((E)-buta-1,3-dienyl)oxy]-2-hydroxymethyl-tetrahydro-pyran-3,4-diol 
• 18549-40-1 1,2-O-isopropylidene-α-D-glucofuranose 
• 72984-63-5 1,3,4,6-tetra-O-acetyl-2-O-benzyl-α- and β-D-glucopyranose 
• 127753-69-9 (E)(prop-2-enal)3-yl 6-O-benzyl-3,4,5-tri-O-acetyl-β-D-glucopyranoside 
• 127753-62-2 (E)buta-1,3-dienyl 2-O-benzyl-3,4,6-tri-O-acetyl-α-D-glucopyranoside 
• 127753-72-4 (E)buta-1,3-dienyl 6-O-benzyl-2,3,4-tri-O-acetyl-α-D-glucopyranoside 
• 127753-57-5 allyl-3-O-allyl-4,6-O-benzylidene-D-glucopyranoside 
• 127753-60-0 (E)(prop-2-enal)-3-yl 2-O-benzyl-3,4,6-tri-O-acetyl-β-D-glucopyranoside 
• 37111-84-5 allyl-3-O-allyl-2-O-benzyl-4,6-O-benzylidene-D-glucopyranoside 
• 109280-59-3 6-O-benzyl-1,2,3,4 tetra-O-acetyl D-glucopyranose 
• 127753-67-7 6-O-Benzyl-2,3,4-tri-O-acetyl-D-glucose 

Downstream Products

• 69551-50-4 (1S,2S)-2-Hydroxymethyl-2-methyl-cyclohexanol 
• 69551-50-4 trans-2-Hydroxymethyl-2-methyl-cyclohexanol 

Relevant academic research and scientific papers

STEREOCHEMICAL VARIATIONS IN AQUEOUS CYCLOADDITIONS USING GLYCO-ORGANIC SUBSTRATES AS A CONSEQUENCE OF CHEMICAL MANIPULATIONS ON THE SUGAR MOIETY

Chemical modifications of the sugar moiety in dienyl glycosides allowed us to rationalize the stereochemistry of our aqueous cycloadditions using glyco-organic substrates.In this way, several dienyl glucosides having benzyl group in 2 or 6 position of the

Aqueous Cycloadditions Using Glyco-Organic Substrates. 1. Stereochemical Course of the Reaction

New water-soluble trans-butadienyl ethers were synthesized by using free glucose as the hydrophilic part.Aqueous cycloaddition with a variety of dienophiles showed rate and stereoselectivity enhancement in comparison with similar peracetylated dienes in o