109280-59-3Relevant academic research and scientific papers
Modifying the regioselectivity of glycosynthase reactions through changes in the acceptor
Stick, Robert V.,Stubbs, Keith A.,Watts, Andrew G.
, p. 779 - 786 (2007/10/03)
Successful glycosynthase-mediated reactions have been performed on 6-O-benzyl-, 6-O-(4-nitrobenzyl)-, and 6-O-benzoyl-D-glucopyranose to give 1,2-β- and 1,3-β-D-glycosylated products; 4-O-benzyl-D-xylopyranose gave only a 1,2-β-glycosylated product. A rat
Asymmetric Diels-Alder Reactions. Part 4. Influence of Anomeric Configuration and 2'- and 6'-O-Benzyl Substitution on the Diastereofacial Reactivity of (E)-3-(t-Butyldimethylsiloxy)-1-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyloxy)-buta-1,3-diene
Larsen, David S.,Stoodley, Richard J.
, p. 1339 - 1352 (2007/10/02)
The 1-(2',3',4',6'-tetra-O-acetyl-α-D-glucopyranosyloxy), 1-(6'-O-benzyl-2',3',4'-tri-O-acetyl-α-D-glucopyranosyloxy), 1-(2'-O-benzyl-3',4',6'-tri-O-acetyl-α-D-glucopyranosyloxy), 1-(6'-O-benzyl-2',3',4'-tri-O-acetyl-β-D-glucopyranosyloxy), and 1-(2'-O-be
STEREOCHEMICAL VARIATIONS IN AQUEOUS CYCLOADDITIONS USING GLYCO-ORGANIC SUBSTRATES AS A CONSEQUENCE OF CHEMICAL MANIPULATIONS ON THE SUGAR MOIETY
Lubineau, Andre,Queneau, Yves
, p. 6697 - 6712 (2007/10/02)
Chemical modifications of the sugar moiety in dienyl glycosides allowed us to rationalize the stereochemistry of our aqueous cycloadditions using glyco-organic substrates.In this way, several dienyl glucosides having benzyl group in 2 or 6 position of the
