106690-87-3

Upstream product

• 67-64-1 acetone 
• 534-85-0 N-phenyl-1,2-benzenediamine 

Downstream Products

• 106690-94-2 4,11-dibromo-5',2'-dihydro-2',2-dimethyl-5,1'-diphenylimidazo<5',4'-2,3>phenazine 
• 106690-88-4 5',2'-dihydro-2',2-dimethyl-5,1'-diphenyl-11-iodoimidazo<5',4'-2,3>phenazine 
• 106691-08-1 3-anilino-1,4-dibromo-2,10-dihydro-2-imino-10-phenylphenazine 
• 90690-82-7 3-anilino-10-phenyl-2,10-dihydro-2-(cyclohexylimino)-phenazine 

Relevant academic research and scientific papers

Imido/nitrene ligands in the complexes of platinum metals

A synthetic search for palladium and platinum complexes with nitrene ligands via reaction of tetranuclear cluster Pd4(μ2-CO)4(μ2-OAc) 4 with nitrosobenzene and reactions of mononuclear complexes [MX4]2- (M=Pt, Pd; X=Cl, NO2) with o-phenylenediamine and its N-phenyl derivative have been carried out. The complexes obtained, [Pd(OAc)o-(PhN)(NO)C6H4]2, Pd[o-(NPh)(N)C6H4]2, Pt[o-(NPh)(N)C6H4]2, Pt2[o-(NPh)(N)C6H4]4[O 3SCF3]2, and Pt2[o-(NPh)(N)C6H4]4Br2, have been structurally characterized by single crystal X-ray diffraction studies. The oxidation of complex Pt[o-(NPh)(N)C6H4]2 by excess AgO3SCF3 afforded a heterotricyclic quinoxaline derivative, whose structure has been determined by X-ray analysis. The data obtained suggest that labile nitrene species coordinated to Pd and Pt complexes are possible intermediates in the reactions under study.