1067-09-0

Basic information

• Product Name: 1,1,1-TRIS(CHLOROMETHYL)ETHANE
• Synonyms: 1,3-DICHLORO-2-(CHLOROMETHYL)-2-METHYLPROPANE;1,1,1-TRIS(CHLOROMETHYL)ETHANE;2-(CHLOROMETHYL)-1,3-DICHLORO-2-METHYLPROPANE;1,3-Dichloro-2-(chloroMethyl)-2-Methylpropane 98%
• CAS NO: 1067-09-0
• Molecular Formula: C₅H₉Cl₃
• Molecular Weight: 175.48
• Mol File: 1067-09-0.mol
• Article Data: 5

Chemical Properties

• Melting Point: 18 °C(lit.)
• Boiling Point: 89-90 °C22 mm Hg(lit.)
• Flash Point: 187 °F
• Appearance: /
• Density: 1.271 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.568mmHg at 25°C
• Refractive Index: n20/D 1.482(lit.)
• CAS DataBase Reference: 1,1,1-TRIS(CHLOROMETHYL)ETHANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1-TRIS(CHLOROMETHYL)ETHANE(1067-09-0)
• EPA Substance Registry System: 1,1,1-TRIS(CHLOROMETHYL)ETHANE(1067-09-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-27-36/37/39
• RIDADR: NA 1993 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 1067-09-0(Hazardous Substances Data)

Usage

General Description

1,3-Dichloro-2-(chloromethyl)-2-methylpropane is a halogenated hydrocarbon. It is formed during the light induced reaction of diazomethane with chloroform.

InChI:InChI=1/C5H9Cl3/c1-5(2-6,3-7)4-8/h2-4H2,1H3

Upstream product

• 2465-56-7 methylene 
• 67-66-3 chloroform 
• 21398-89-0 2-methoxymethyl-2-methyl-1,3-propanediol 
• 3143-02-0 3-hydroxymethyl-3-methyloxethane 
• 98-07-7 Benzotrichlorid 
• 19256-62-3 5-(methoxymethyl)-2,2,5-trimethyl-1,3-dioxane 
• 3663-46-5 5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane 
• 82925-86-8 5-chloromethyl-5-methyl-2-thia-1,3-dioxane 2-oxide 
• 77-85-0 2-(hydroxymethyl)-2-methylpropane-1,3-diol 
• 186581-53-3 diazomethane 

Downstream Products

• 1001-75-8 4-methyl-4-pentenoic acid 
• 18540-98-2 3-(diphenylphosphanyl-methyl)-3-methyl-1,1-diphenyl-phosphetanium; chloride 
• 155932-49-3 H₃CC{CH₂P(C₆H₄C₄H₉)2}3 
• 22031-15-8 1,1,1-tris(di(4-methylphenyl)phosphinomethyl)ethane 
• 155932-48-2 methyl(2-methyldiphenylphosphino)-1-chloro-3-diphenylphosphinopropane 
• 126150-68-3 (2-methyl-2-((phenylthio)methyl)propane-1,3-diyl)bis(diphenylphosphane) 
• 129521-04-6 (2-methyl-3-(phenylthio)-2-((phenylthio)methyl)propyl)diphenylphosphane 
• 79190-90-2 (CO)3(1,1,1-tris(diphenylphosphinomethylene)ethane)Mo 
• 1436683-93-0 C₃₅H₄₆BP₃ 
• 1436684-20-6 1-(diisopropylphosphinomethyl)-1,1-bis(diphenylphosphinomethyl)ethane 
• 1436684-32-0 [MoI₃(1-(diisopropylphosphinomethyl)-1,1-bis(diphenylphosphinomethyl)ethane)] 
• 1370793-50-2 1,1,1-tris{[bis(4-dimethylaminophenyl)phosphino]methyl}ethane 

Relevant articles and documents

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Method for Chlorinating Alcohols

A process for preparing organic chlorides in which the chlorine atom is bonded to a CH2 group by reacting the corresponding alcohols with thionyl chloride in the presence of a triaylphosphine oxide at a temperature of from 20 to 200° C. and a pressure of from 0.01 to 10 MPa abs, which comprises using the triarylphosphine oxide in a molar ratio to the amount of OH groups to be chlorinated of from 0.0001 to 0.5.

UNUSUAL TRIPOD-LIKE LIGANDS. SYNTHESIS OF 2,2-BIS(DIPHENYLPHOSPHINOMETHYL)-1-METHOXYPROPANE AND 2,2-BIS(PHENYLTHIOMETHYL)-1-METHOXYPROPANE

By employment of 1,1,1-tris(hydroxymethyl)ethane as the starting material, syntheses of two novel tripod-like terdentates with mixed donor properties, 2,2-Bis(diphenylphosphinomethyl)-1-methoxypropane (P2O) and 2,2-Bis(diphenylphosphinomethyl)-1-methoxypropane (S2O) are reported.Structural confirmation is based on spectroscopic and analytical results.Key words: tripodal ligands; terdentates; organophosphine ligand; organosulfur ligand.