1067-10-3

Basic information

• Product Name: BROMOTRIETHYLGERMANE
• Synonyms: TRIETHYLGERMANIUM BROMIDE;TRIETHYLBROMOGERMANE;BROMOTRIETHYLGERMANE;BromotriethylgermaneTriethylgermanium bromide
• CAS NO: 1067-10-3
• Molecular Formula: C₆H₁₅BrGe
• Molecular Weight: 239.73
• EINECS: 213-614-0
• Mol File: 1067-10-3.mol
• Article Data: 3

Chemical Properties

• Melting Point: -33 °C
• Boiling Point: 190.9 °C
• Flash Point: 38 °C
• Appearance: /liquid
• Density: 1.4
• Vapor Pressure: 2.2mmHg at 25°C
• Refractive Index: 1.4829
• Storage Temp.: Flammables area
• CAS DataBase Reference: BROMOTRIETHYLGERMANE(CAS DataBase Reference)
• NIST Chemistry Reference: BROMOTRIETHYLGERMANE(1067-10-3)
• EPA Substance Registry System: BROMOTRIETHYLGERMANE(1067-10-3)

Safety Data

• Hazard Codes: Xn
• Statements: 36/37/38-20/21/22-10
• Safety Statements: 37/39-26-16
• RIDADR: 3265
• TSCA: No
• Hazardous Substances Data: 1067-10-3(Hazardous Substances Data)

Usage

Description

Triethylgermanium Bromide is a kind of organic bromide are useful reagent, catalyst, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others. It is also reagent for the formation of dienolates of α, β-unsaturated esters, and is also useful for methylenecyclopentane annulation reactions.

InChI:InChI=1/C6H15BrGe/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3

Upstream product

• 5167-96-4 Tris-(triethylgermyl)-stiben 
• 100-39-0 benzyl bromide 
• 4149-28-4 bis(triethylgermyl)mercury 
• 70-11-1 α-bromoacetophenone 
• 598-22-1 propanoyl bromide 
• 181476-24-4 tributyl(triethylgermyl)stannane 
• 106-95-6 allyl bromide 
• 1188-14-3 Triethylgerman 
• 72084-30-1 1-triethylgermyloxy-1-tert-butylethene 
• 994-28-5 triethylchlorogermane 

Downstream Products

• 100-39-0 benzyl bromide 
• 994-28-5 triethylchlorogermane 
• 1188-14-3 Triethylgerman 
• 57454-43-0 triethyl(phenylthio)germane 
• 35406-49-6 bis[tris(pentafluorophenyl)germyl]mercury 
• 42371-50-6 tris(pentafuorophenyl)germane 
• 59871-30-6 1,1,1-Triethyl-2,2,2-tris-pentafluorophenyl-digermane 
• 98039-87-3 triethyl(p-tolylthio)germane 
• 78599-94-7 phenyl(triethylgermyl)acetonitrile 
• 184483-90-7 triethylgermyl (trifluoroacetoxy)phenylacetate 
• 13314-51-7 triethyl(iodo)germane 
• 102881-05-0 1-triethylgermyl-4-ethylbenzene 
• 723-06-8 3-triethylgermyl-1-trifluoromethylbenzene 
• 565215-04-5 4-triethylgermylmethylstyrene 

Relevant articles and documents

Palladium complex-catalyzed germylation of allylic halides using (germyl)stannanes

(Triethylgermyl)tributylstannane reacts metal-selectively with allylic halides at room temperature (r.t.) in the presence of tris(dibenzylideneacetone)dipalladium, Pd2(dba)3CHCl3, to provide an alternative route to allylge

METAL-HALOGEN BONDING STUDIES WITH GROUP IV A TRIALKYLMETAL HALIDES

Halogen redistribution reactions have been found to take place between benzyl bromide or benzyl iodide and the Group IV A silicon, germanium, tin, and lead containing trialkylmetal chlorides.However, for the reactions of the Si, Ge and Sn compounds, a quaternary ammonium halide catalyst was necessary to enable the equilibria to be established at reasonably rapid rates.The equilibrium constants at 50 deg C have been measured for each of these halogen redistributions.They have been found to increase gradually on going down in Group IV A from silicon to lead, being conside rably less than unity in the case of silicon and somewhat greater than unity in the case of lead for both the R3MCl + BzBr and R3MCl + BzI reactions.The ΔG0 values for these equilibria have been calculated, and it is suggested that their differences may be explained in terms of the relative importance of p?-d? contributions to the halogen-metal bonding in the various Group IV A trialkylmetal halide systems.