2945-41-7

Basic information

• Product Name: benzyl(triethyl)germane
• Synonyms: Germane, triethyl(phenylmethyl)-
• CAS NO: 2945-41-7
• Molecular Formula: C₁₃H₂₂Ge
• Molecular Weight: 250.9538
• Mol File: 2945-41-7.mol

Chemical Properties

• Boiling Point: 277.9°C at 760 mmHg
• Flash Point: 115.8°C
• Vapor Pressure: 0.00743mmHg at 25°C
• CAS DataBase Reference: benzyl(triethyl)germane(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl(triethyl)germane(2945-41-7)
• EPA Substance Registry System: benzyl(triethyl)germane(2945-41-7)

Safety Data

• Hazardous Substances Data: 2945-41-7(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 1067-10-3 Bromotriethylgermanium 
• 1589-82-8 phenylmagnesium bromide 
• 34241-82-2 triethylgermylpotassium 
• 100-44-7 benzyl chloride 
• 43106-47-4 Triethylgermyl-natrium 
• 6921-34-2 benzylmagnesium chloride 

Downstream Products

• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 109021-87-6 3-(triethylgermyl)cyclohexene 
• 109021-86-5 1-(triethylgermyl)cyclohexene 
• 109021-85-4 triethylgermylcyclohexane 
• 993-62-4 hexaethyldigermane 
• 109021-95-6 2,3-dimethyl-3-(triethylgermyl)-1-butene 
• 109021-94-5 2,3-dimethyl-2-(triethylgermyl)butane 
• 109021-93-4 2,2,3-trimethyl-4-phenyl-2-(trimethylgermyl)butane 
• 2538-70-7 hexaethyldigermoxane 
• 109021-96-7 2,3-dimethyl-3-benzyl-4-triethylgermyl-1-butene 
• 25922-49-0 1-triethylgermyl-2-hexene 
• 109021-82-1 1-triethylgermyl-2-benzylhexane 
• 3634-46-6 1-triethylgermylhexane 
• 25922-48-9 1-triethylgermyl-1-hexene 

Relevant articles and documents

General access to para-substituted styrenes

A simple and efficient procedure has been developed for the synthesis of organogermanium compounds and styrenes para-substituted with groups containing an atom of the 14th group by one-pot reaction of halogenosilanes, germanes or stannanes, organic halides and magnesium using ultrasound methods.

General access to para-substituted styrenes

A simple and efficient procedure has been developed for the synthesis of organogermanium compounds and styrenes para-substituted with groups containing an atom of the 14th group by one-pot reaction of halogenosilanes, germanes or stannanes, organic halides and magnesium using ultrasound methods.

Reactivities of triethylgermylborate in methanol

The reactivity of lithium (triethylgermyl)triphenylborate, prepared from unsolvated triethylgermyllithium and triphenylborane, with organic substrates in methanol was investigated. The germylborates reacted with organic halides and acyl halides to give th

Photochemical Addition of Benzyltriethylgermane and Dibenzyldiethylgermane to Olefines

A novel photochemical addition of a germanyl radical to the olefinic double bond was discovered when benzyltriethylgermane or dibenzyldiethylgermane was irradiated with a medium-pressure mercury lamp in the presence of olefins.

THE INFLUENCE OF THE MAGNETIC FIELD AS A TOOL FOR INVESTIGATION OF THE MECHANISM OF REACTIONS OF TRIETHYLGERMYL RADICALS

The influence of the external magnetic field on the product yield in the reaction of Et3GeM (where M = Na, K) with benzyl chloride was investigated.A mechanism for magnetic effects in this reaction is proposed.To verify the mechanism proposed, theoretical calculations of the recombination probability of triethylgermyl and benzyl singlet radical pairs were carried out.It is proposed that associated state of the organometallic compound in solution affects the cage and the magnetic effects.