1067583-19-0

Basic information

• Product Name: N-methylmorpholinium 1-amino-2,4-dicyano-4-ethoxycarbonyl-1,3-butadienethiolate
• Synonyms: N-methylmorpholinium 1-amino-2,4-dicyano-4-ethoxycarbonyl-1,3-butadienethiolate
• CAS NO: 1067583-19-0
• Molecular Weight: 324.404
• Mol File: 1067583-19-0.mol

Chemical Properties

• CAS DataBase Reference: N-methylmorpholinium 1-amino-2,4-dicyano-4-ethoxycarbonyl-1,3-butadienethiolate(CAS DataBase Reference)
• NIST Chemistry Reference: N-methylmorpholinium 1-amino-2,4-dicyano-4-ethoxycarbonyl-1,3-butadienethiolate(1067583-19-0)
• EPA Substance Registry System: N-methylmorpholinium 1-amino-2,4-dicyano-4-ethoxycarbonyl-1,3-butadienethiolate(1067583-19-0)

Safety Data

• Hazardous Substances Data: 1067583-19-0(Hazardous Substances Data)

Upstream product

• 109-02-4 4-methyl-morpholine 
• 503621-72-5 cyanothioacetamide 
• 42466-67-1 ethyl (ethoxymethylene)cyanoacetate 

Downstream Products

• 919749-54-5 7-cyano-3-(3,4-dimethylphenyl)-6-thioxo-1,3,4,6-tetrahydro-2H-pyrido[1,2-a][1,3,5]triazine-9-carboxylic acid ethyl ether 
• 1067583-24-7 7-cyano-3-phenyl-6-thioxo-1,3,4,6-tetrahydro-2H-pyrido[1,2-a][1,3,5]triazine-9-carboxylic acid ethyl ether 
• 919720-63-1 7-cyano-3-(2-ethoxyphenyl)-6-thioxo-1,3,4,6-tetrahydro-2H-pyrido[1,2-a][1,3,5]triazine-9-carboxylic acid ethyl ether 
• 919733-56-5 7-cyano-3-(4-fluorophenyl)-6-thioxo-1,3,4,6-tetrahydro-2H-pyrido[1,2-a][1,3,5]triazine-9-carboxylic acid ethyl ether 

Relevant articles and documents

The Mannich reaction in the synthesis of N,S-containing heterocycles 3. Unexpected direction of the aminomethylation reaction of N-methylmorpholinium 1-amino-2,4-dicyano-4-ethoxycarbonyl-1,3-butadienethiolate. One stage cascade synthesis of new derivatives of pyrido[1,2-a][1,3,5]triazine

The interaction of N-methylmorpholinium 1-amino-2,4-dicyano-4- ethoxycarbonyl-1,3-butadienethiolate with primary amines and formaldehyde leads to the formation of ethyl esters of 7-cyano-6-thioxo-1,3,4,6-2H-pyrido[1,2-a][1, 3,5]triazine-9-carboxylic acid in place of the expected derivatives of pyrido[2,1-b][1,3,5]thiadiazine. The structure of the ethyl ester of 7-cyano-3-phenyl-6-thioxo-1,3,4,6-2H-pyrido[1,2-a][1,3,5]triazine-9-carboxylic acid was demonstrated by X-ray structural analysis.