106865-15-0Relevant academic research and scientific papers
Zwitterionic Nickel(II) Catalyst for CO-Ethylene Alternating Copolymerization
Jia, Xiaofei,Zhang, Mengru,Pan, Fan,Babahan, Ilknur,Ding, Kuiling,Jia, Li,Crandall, Laura A.,Ziegler, Christopher J.
, p. 4798 - 4801 (2015)
A zwitterionic nickel(II) catalyst has been discovered to display an initial catalytic activity comparable to that of cationic palladium catalysts for alternating copolymerization of carbon monoxide and ethylene. This demonstrates the absence of a severe
Palladium-Catalyzed Coupling of Aryl Halides with (Trimethylstannyl)diphenylphosphine and (Trimethylsilyl)diphenylphosphine
Tunney, S. E.,Stille, J. K.
, p. 748 - 753 (2007/10/02)
The palladium-catalyzed reaction of aryl halides with either (trimethylsilyl)diphenylphosphine or (trimethylstannyl)diphenylphosphine gives aryldiphenylphosphines in good yields, under relatively mild conditions (50-70 deg C, benzene).The reaction tolerates a number of functional groups including methyl ethers, esters, ketones, nitriles, anilides, and certain halogens.The nitro and aldehyde groups as well as compounds containing groups such as amino and hydroxyl are not tolerated.
